3-benzylsulfanylmethyl-3-methyl-oxetane

Base Information

Chemical Name:3-benzylsulfanylmethyl-3-methyl-oxetane
CAS No.:195450-55-6
Molecular Formula:C₁₂H₁₆OS
Molecular Weight:208.324
Hs Code.:

Synonyms:3-benzylsulfanylmethyl-3-methyl-oxetane

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Chemical Property of 3-benzylsulfanylmethyl-3-methyl-oxetane

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Technology Process of 3-benzylsulfanylmethyl-3-methyl-oxetane

There total 1 articles about 3-benzylsulfanylmethyl-3-methyl-oxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 3864-43-5
methanesulfonic acid 3-methyloxetan-3-ylmethyl ester

: 100-53-8
phenylmethanethiol

: 195450-55-6
3-benzylsulfanylmethyl-3-methyl-oxetane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; for 12h; Ambient temperature;
DOI:10.1002/cber.19971300917

Reference yield: 92.0%

: 195450-55-6
3-benzylsulfanylmethyl-3-methyl-oxetane

: (3-Methyl-5-phenyl-tetrahydro-thiophen-3-yl)-methanol

Guidance literature:: With piperidine; n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; for 2h;
DOI:10.1002/cber.19971300917

Reference yield: 92.0%

: 13283-31-3
borane

: 124-63-0
methanesulfonyl chloride

: 829-85-6
diphenylphosphane

: 195450-55-6
3-benzylsulfanylmethyl-3-methyl-oxetane

: (+/-)methanesulfonic acid-3-benzylsulfanyl-2-diphenylphosphanylmethyl-2-methyl-1-propylesterborane

Guidance literature:: With n-BuLi; NEt₃; In tetrahydrofuran; dichloromethane; Ar-atmosphere; mixing HPPh2 with BuLi (in THF) at 0°C, stirring for 30 min, addn. of oxetane (in THF), refluxing for 2 h, treatment with BH3 at 20°C, stirring for 1 h, evapn., dissoln. in CH2Cl2, addn. of NEt3, CH3SO2Cl and H2O (pH=4.5); extn. of aq. phase into CH2Cl2, drying of org. phase, concn., chromy. (SiO2, petroleum ether/Et2O=4:6); elem. anal.;
DOI:10.1016/S0020-1693(97)05784-8