[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

Base Information

Chemical Name:[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4
CAS No.:1130382-23-8
Molecular Formula:C₂₄BF₂₀*C₂₅H₃₀CuN₄O
Molecular Weight:1145.13
Hs Code.:

[Cu(I)(bis(2-pycolyl)amine(C<sub>6</sub>H<sub>3</sub>-2-OMe-5-t-Bu))(acetonitrile)]B(C<sub>6</sub>F<sub>5</sub>)4

Synonyms:[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

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Chemical Property of [Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

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Technology Process of [Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

There total 1 articles about [Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 425370-02-1
tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

: 1130382-43-2
⁽⁰⁾L

: 1130382-23-8
[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

Guidance literature:: In diethyl ether; under Ar; ligand dissolved in O2-free Et2O; Cu complex added slowly; pptd. by O2-free pentane; supernatant decanted; powder dried under vac.;dissolution and pptn. in Et2O and pentane and vac. drying repeated 3-5 times; elem. anal.;

Reference yield: 74.0%

: 1130382-23-8
[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

: 80937-33-3
oxygen

: 108-88-3,15644-74-3,16713-13-6
toluene

: [di-μ-hydroxydicopper(II)(bis(2-pycolyl)amine(C6H3-2-OMe-5-t-Bu))2][B(C6F5)4]2*0.8(toluene)

Guidance literature:: In toluene; under Ar; Cu complex dissolved in O2-free CH2Cl2; cooled to -80°C(dry ice-acetone bath); O2 gently bubbled for ca. 1 min; excess O2 remo ved by purging with Ar for 2-3 min; warmed to ambient temp.; filtered; ppt. collected; elem. anal.;

Reference yield: 45.0%

: 75-09-2
dichloromethane

: 1130382-23-8
[Cu(I)(bis(2-pycolyl)amine(C₆H₃-2-OMe-5-t-Bu))(acetonitrile)]B(C₆F₅)4

: 80937-33-3
oxygen

: 1130382-35-2
Cu(N(CH₂C₅H₄N)2C₆H₃(OCH₃)C(CH₃)3)Cl⁽¹⁺⁾*B(C₆F₅)4^(1-)*CH₂Cl₂=(Cu(N(CH₂C₅H₄N)2C₆H₃(OCH₃)C(CH₃)3)Cl)B(C₆F₅)4*CH₂Cl₂

Guidance literature:: In dichloromethane; under Ar; Cu complex dissolved in O2-free CH2Cl2; cooled to -80°C(dry ice-acetone bath); O2 gently bubbled; excess O2 removed by purging with Ar for 2-3 min; warmed to ambient temp.; kept overnight; solid collected; elem. anal.;