methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside
CAS No.:357399-53-2
Molecular Formula:C₂₆H₃₅NO₁₁S₃
Molecular Weight:633.762
Hs Code.:

Synonyms:methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

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Chemical Property of methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

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Technology Process of methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

There total 5 articles about methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 124-63-0
methanesulfonyl chloride

: 357399-52-1
methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-1-thio-β-D-glucopyranoside

: 357399-53-2
methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

Guidance literature:: With pyridine; In dichloromethane; at 0 - 20 ℃; for 20h;
DOI:10.1021/jo010210+

Reference yield:

: 282525-99-9
methyl 4,6-O-benzylidene-2-deoxy-2-N-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]amino-1-thio-β-D-glucopyranoside

: 357399-53-2
methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridine; 4-(dimethylamino)pyridine / 16 h / 20 °C

2: 76 percent / acetic acid; water / 1 h / 65 °C

3: 61 percent / pyridine / CH₂Cl₂ / 20 h / 0 - 20 °C

With pyridine; dmap; water; acetic acid; In dichloromethane;
DOI:10.1021/jo010210+

Reference yield:

: methyl 3-O-benzoyl-4,6-O-benzylidene-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-1-thio-β-D-glucopyranoside

: 357399-53-2
methyl 3-O-benzoyl-2-(1-(4,4-dimethyl-2,6-dioxocyclohexylidene)ethylamino)-2-deoxy-4,6-bis-O-(methanesulfonyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / acetic acid; water / 1 h / 65 °C

2: 61 percent / pyridine / CH₂Cl₂ / 20 h / 0 - 20 °C

With pyridine; water; acetic acid; In dichloromethane;
DOI:10.1021/jo010210+