(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

Base Information

Chemical Name:(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium
CAS No.:700817-09-0
Molecular Formula:C₂₇H₃₂ClIrN₂
Molecular Weight:612.237
Hs Code.:

Synonyms:(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

Suppliers and Price of (1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

There total 1 articles about (1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 700816-99-5
1-isopropyl-3-methyl-2,4-diphenylimidazolium iodide

: 700817-09-0
(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

Guidance literature:: With silver acetate; Ag₂O; HCl; In dichloromethane; water; acetone; byproducts: acetic acid; AgO2CCH3 was added to soln. of iodide in Me2CO/H2O (1/1); stirred for 30min; filtered; aq. HCl added; filtered; heated at 50°C in vac. f or 1 h; residue stirred with Ag2O in CH2Cl2 in dark for 1.5 h; filtered;Ir complex added; stirred for 1 h; filtered through Celite; volatiles removed; chromd. (silica gel, EtOAc/hexane, 1/1); elem. anal.;
DOI:10.1021/om049903h

Reference yield: 91.0%

: 700817-09-0
(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

: 201230-82-2
carbon monoxide

: 700817-17-0
(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)dicarbonylchloroiridium

Guidance literature:: In dichloromethane; CO was passed through soln. of Ir complex in CH2Cl2 for 10 min; solvent removed (vac.); washed (pentane); dried (vac.); elem. anal.;
DOI:10.1021/om049903h

Reference yield: 52.0%

: 17084-13-8
potassium hexafluorophosphate

: 75-09-2
dichloromethane

: 700817-09-0
(1-isopropyl-3-methyl-2,4-diphenylimidazolin-5-ylidene)[(1,2,5,6-η)-1,5-cyclooctadiene]chloroiridium

: bis(1,4-dimethyl-1,2,4-triazol-5-ylidene)silver(I) hexafluorophosphate

: (1,4-dimethyl-1,2,4-triazol-5-ylidene)(1-isopropyl-2,4-diphenyl-3-methylimidazol-5-ylidene)(η4-1,5-cyclooctadiene)iridium(I) hexafluorophosphate dichloromethane solvate

Guidance literature:: In dichloromethane; combining of (Ag(1,4-dimethyl-1,2,4-triazol-5-ylidene)2)PF6 (0.8 equiv.)with IrCl(COD)(1-isopropyl-2,4-diphenyl-3-methylimidazol-5-ylidene) and KPF6 in flask; placing under inert atmosphere; addn. of CH2Cl2; stirrin g at room temp. in the dark for 24 h; removal of solvent under vac., chromy. (50:50 ethyl acetate/hexanes and then by 100% ethyl acetate); recrystn. from CH2Cl2/pentane; as mixt. of diastereomers; elem. anal.;
DOI:10.1016/j.jorganchem.2008.05.024