ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

Base Information

Chemical Name:ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate
CAS No.:85083-36-9
Molecular Formula:C₁₆H₂₀BrNO₆
Molecular Weight:402.242
Hs Code.:

Synonyms:ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

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Chemical Property of ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

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Technology Process of ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

There total 7 articles about ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 37517-78-5
magnesium bis(3-ethoxy-3-oxopropanoate)

: 85083-38-1
N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-4-aminobutyric acid

: 85083-36-9
ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

Guidance literature:: With 1,1'-carbonyldiimidazole; In tetrahydrofuran; for 27.5h;
DOI:10.1021/ja00347a055

Reference yield: 39.0%

: 85083-30-3
ethyl N-(2-bromo-3,6-dihydroxy-4-methoxy-5-methylphenyl)-(E)-α-2-pyrrolidinylideneacetate

: 85083-37-0
8-bromo-9a-<(ethoxycarbonyl)methyl>-1,2,3,6,7,9a-hexahydro-6,7-dioxopyrrolo<2,1-b>benzoxazole

: 85083-36-9
ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

Guidance literature:: With hydrogenchloride; iron(III) chloride; In methanol;
DOI:10.1021/ja00347a055

Reference yield:

: 2207-57-0
2-methoxy-3-methyl-1,4-benzoquinone

: 85083-36-9
ethyl N-(2-bromo-6-methoxy-5-methyl-1,4-benzoquinonyl)-3-oxo-6-aminocaproate

Guidance literature:: Multi-step reaction with 6 steps

1: aq. Na₂S₂O₄, pH 7.0 / CHCl₃

2: bromine / CHCl₃ / 0.33 h

3: aq. FeCl₃, HCl / methanol / 0.17 h

4: 98 percent / potassium carbonate / benzene / 10 h

5: 57 percent / benzene / 0.07 h / Irradiation

6: 39 percent / aq. FeCl₃, HCl / methanol

With hydrogenchloride; sodium dithionite; bromine; iron(III) chloride; potassium carbonate; In methanol; chloroform; benzene;
DOI:10.1021/ja00347a055