2207-57-0

Basic information

• Product Name: 2-METHOXY-3-METHYL-[1,4]BENZOQUINONE
• Synonyms: 2-METHOXY-3-METHYL-[1,4]BENZOQUINONE;2,5-Cyclohexadiene-1,4-dione, 2-Methoxy-3-Methyl-
• CAS NO: 2207-57-0
• Molecular Formula: C₈H₈O₃
• Molecular Weight: 152.14732
• Mol File: 2207-57-0.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-METHOXY-3-METHYL-[1,4]BENZOQUINONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHOXY-3-METHYL-[1,4]BENZOQUINONE(2207-57-0)
• EPA Substance Registry System: 2-METHOXY-3-METHYL-[1,4]BENZOQUINONE(2207-57-0)

Safety Data

• Hazardous Substances Data: 2207-57-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 4917, 1984 DOI: 10.1016/S0040-4039(01)91258-4

Upstream product

• 72796-36-2 2-Methyl-3,4,4-trimethoxycyclohexa-2,5-dienone 
• 5673-07-4 2,6-dimethoxytoluene 
• 1760-80-1 2-methoxy-3-methylbenzene-1,4-diol 
• 7577-74-4 6-acetoxy-6-methylcyclohexa-2,4-dienone 
• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 
• 608-25-3 2-methylbenzene-1,3-diol 
• 7149-92-0 2,4-dimethoxy-3-methylbenzaldehyde 
• 96502-90-8 acetic acid 2,4-dimethoxy-3-methyl-phenyl ester 
• 60512-80-3 2′,4′-dimethoxy-3′-methylacetophenone 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 4463-33-6 1,2-dimethoxy-3-methylbenzene 
• 578-58-5 2-methylmethoxybenzene 
• 109685-08-7 4-hydroxy-3-methoxy-2-methylbenzyl alcohol 

Downstream Products

• 408349-27-9 3-methoxy-4-methyl-2-(2,4,5-trimethoxy-3-methyl-anilino)-benzoic acid 
• 77357-37-0 2-Methoxy-5-(1-pyrrolidinyl)-1,4-benzoquinone 
• 77357-36-9 2-Methoxy-3-methyl-6-(1-pyrrolidinyl)-1,4-benzoquinone 
• 77357-35-8 2-Methoxy-3-methyl-5-(1-pyrrolidinyl)-1,4-benzoquinone 
• 77357-38-1 2-(1-Pyrrolidinyl)-3-methyl-5-(1-pyrrolidinyl)-1,4-benzoquinone 
• 79664-59-8 2,5-dimethyl-6-methoxy-4,7-dihydroisoindole-4,7-dione 
• 77357-45-0 5-Bromo-5-methyl-6-methoxy-6-acetoxycyclohex-2-ene-1,4-dione 
• 202344-74-9 5-anilino-2-methoxy-3-methyl-1,4-benzoquinone 
• 1760-80-1 2-methoxy-3-methylbenzene-1,4-diol 
• 622852-28-2 2,5-dihydroxy-4-methoxy-3-methyl-benzaldehyde 
• 526217-76-5 1-bromo-2,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-3-methyl-benzene 
• 526217-79-8 [2,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-3-methyl-phenyl]-acetic acid 
• 526217-78-7 [2,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-3-methyl-phenyl]-acetic acid ethyl ester 
• 526217-85-6 (5E,7Z)-(2R,4S)-2-[2,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-3-methyl-phenyl]-4-methyl-nona-5,7-dienal 

Relevant articles and documents

Regiodivergent oxidation of alkoxyarenes by hypervalent iodine/oxone system

We have found that the combination of Oxone with an organoiodine compound, i.e., 2-iodobenzoic acid (2-IB), selectively yields p-quinones from monomethoxyarenes under mild conditions. In this reaction system, an organoiodine compound is immediately oxidized by Oxone to generate cyclic hypervalent iodine (III) species in situ, which serves as the specific mediator for the selective p-quinone synthesis, preventing o-quinone formation.

Combined C-H activation/cope rearrangement as a strategic reaction in organic synthesis: Total synthesis of (-)-colombiasin A and (-)-elisapterosin B

The total synthesis of (-)-colombiasin A (2) and (-)-elisapterosin B (3) has been achieved. The key step is a C-H functionalization process, the combined C-H activation/Cope rearrangement, between methyl (E)-2-diazo-3-pentenoate and 1-methyl-1,2-dihydrona

Efficient and green telescoped process to 2-methoxy-3-methyl-[1,4] benzoquinone

A telescoped process for the preparation of 2-methoxy-3-methyl-[1,4] benzoquinone is disclosed. When this novel process is compared to the prevailing method that utilizes Na2Cr2O7 as the oxidant, the novel process represen