N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

Base Information

Chemical Name:N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide
CAS No.:955116-94-6
Molecular Formula:C₂₂H₃₂N₂O₅S
Molecular Weight:436.572
Hs Code.:

Synonyms:N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

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Chemical Property of N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

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Technology Process of N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

There total 5 articles about N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 75-91-2
tert.-butylhydroperoxide

: 955116-92-4
N-{2-[1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

: 955116-94-6
N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

Guidance literature:: With 3 A molecular sieve; manganese triacetate; In decane; acetonitrile; at 20 ℃; for 24h;
DOI:10.1021/ol701493k

Reference yield:

: 57638-94-5
ethanesulfonic acid biphenyl-2-ylamide

: 955116-94-6
N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-BuLi / hexane; tetrahydrofuran / 0.5 h / -78 °C

1.2: Li; NH₃ / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.3: 70 percent / tetrahydrofuran; hexane / 0.17 h / -78 °C

2.1: LiAlH₄; AlCl₃ / tetrahydrofuran / 4 h / 20 °C

3.1: 0.695 g / Et₃N / CH₂Cl₂ / 12 h / 20 °C

4.1: 60 percent / 3 Angstroem molecular sieves; Mn(OAc)3*2H₂O / acetonitrile; decane / 24 h / 20 °C

With lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; 3 A molecular sieve; manganese triacetate; triethylamine; In tetrahydrofuran; decane; hexane; dichloromethane; acetonitrile;
DOI:10.1021/ol701493k

Reference yield:

: 955116-98-0
ethanesulfonic acid {2-[1-(2-aminoethyl)-cyclohexa-2,5-dienyl]phenyl}amide

: 955116-94-6
N-{2-[4-tert-butylperoxy-1-(2-ethanesulfonylamino-phenyl)-cyclohexa-2,5-dienyl]ethyl}acetamide

Guidance literature:: Multi-step reaction with 2 steps

1: 0.695 g / Et₃N / CH₂Cl₂ / 12 h / 20 °C

2: 60 percent / 3 Angstroem molecular sieves; Mn(OAc)3*2H₂O / acetonitrile; decane / 24 h / 20 °C

With 3 A molecular sieve; manganese triacetate; triethylamine; In decane; dichloromethane; acetonitrile;
DOI:10.1021/ol701493k