4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

Base Information

Chemical Name:4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide
CAS No.:1578270-28-6
Molecular Formula:C₂₅H₃₇NO₃SSi
Molecular Weight:459.725
Hs Code.:

Synonyms:4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

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Chemical Property of 4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

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Technology Process of 4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

There total 2 articles about 4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 994-30-9
triethylsilyl chloride

: 1578270-15-1
N-((1R,3S)-1-hydroxy-1-phenylhex-5-en-3-yl)-4-methylbenzenesulfonamide

: 1578270-28-6
4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2014.02.001

Reference yield:

: 1578270-14-0
(3S,5R)-3-allyl-5-phenyl-2-tosylisoxazolidine

: 1578270-28-6
4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: molybdenum hexacarbonyl / water; acetonitrile / 0.25 h / 20 °C

1.2: 90 °C

2.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

With triethylamine; molybdenum hexacarbonyl; In dichloromethane; water; acetonitrile;
DOI:10.1016/j.tet.2014.02.001

Reference yield: 91.0%

: 201230-82-2
carbon monoxide

: 1578270-28-6
4-methyl-N-((1R,3S)-1-phenyl-1-((triethylsilyl)oxy)hex-5-en-3-yl)benzenesulfonamide

: 1578270-29-7
(S)-2-((R)-2-phenyl-2-((triethylsilyl)oxy)ethyl)-1-tosyl-1,2,3,4-tetrahydropyridine

Guidance literature:: With dirhodium tetraacetate; hydrogen; 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin); In toluene; at 85 ℃; for 22h; under 3102.97 Torr; Reagent/catalyst; Catalytic behavior; Sealed tube;
DOI:10.1016/j.tet.2014.02.001