beta-Pyrufuran

Base Information

Chemical Name:beta-Pyrufuran
CAS No.:88256-04-6
Molecular Formula:C₁₅H₁₄O₅
Molecular Weight:274.273
Hs Code.:
DSSTox Substance ID:DTXSID80236926
Nikkaji Number:J591.332B
Wikidata:Q27108638
Metabolomics Workbench ID:44481

Synonyms:beta-Pyrufuran;1,2,4-Trimethoxydibenzofuran-3-ol;88256-04-6;3-Dibenzofuranol, 1,2,4-trimethoxy-;1,2,4-Trimethoxy-3-dibenzofuranol;b-Pyrufuran;.beta.-Pyrufuran;Trimethoxydibenzofuran-ol;C08948;CHEBI:10439;DTXSID80236926;1,2,4-trimethoxy-dibenzofuran-3-ol;1,2,4-Trimethoxydibenzo[b,d]furan-3-ol;1,2,4-Trimethoxy-3-dibenzofuranol, 9CI;1,2,4-Trimethoxydibenzo[b,d]furan-3-ol #;Q27108638;3,4,6-trimethoxy-8-oxatricyclo[7.4.0.0^{2,7}]trideca-1(13),2,4,6,9,11-hexaen-5-ol

Suppliers and Price of beta-Pyrufuran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of beta-Pyrufuran

Chemical Property:

Vapor Pressure:1.77E-08mmHg at 25°C
Boiling Point:443.5°C at 760 mmHg
Flash Point:222°C
Density:1.3g/cm³
XLogP3:3.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:274.08412354
Heavy Atom Count:20
Complexity:336

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=C(C2=C1C3=CC=CC=C3O2)OC)O)OC

Technology Process of beta-Pyrufuran

There total 6 articles about beta-Pyrufuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88256-07-9
1,2,3,4-tetramethoxydibenzofuran

: 88256-04-6
β-pyrufuran

: 88256-05-7
1,3,4-trimethoxydibenzofuran-2-ol

Guidance literature:: With boron trichloride; In dichloromethane; for 4.5h; Yield given. Title compound not separated from byproducts; Ambient temperature;

Reference yield:

: 23030-39-9
1-bromo-2,3,5-trimethoxybenzene

: 88256-04-6
β-pyrufuran

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaOMe, 2.) CuCl / 1.) MeOH,benzene, 2.) pyridine, reflux, 20 h

2: 46 percent / Pd(OAc)2 / trifluoroacetic acid; acetic acid / 2.3 h / Heating

3: 11 percent / 1.) n-BuLi, 2.) lithium salt of t-butylperoxide / 1.) n-hexane, Et₂O, 4 deg C, 48 h, 2.) -78 deg C -> RT, then reflux, 5 min

With palladium diacetate; n-butyllithium; lithium tert-butyl hydroperoxide; sodium methylate; copper(l) chloride; In acetic acid; trifluoroacetic acid;

Reference yield:

: 88037-84-7
2,3,5-trimethoxydiphenyl ether

: 88256-04-6
β-pyrufuran

Guidance literature:: Multi-step reaction with 2 steps

1: 46 percent / Pd(OAc)2 / trifluoroacetic acid; acetic acid / 2.3 h / Heating

2: 11 percent / 1.) n-BuLi, 2.) lithium salt of t-butylperoxide / 1.) n-hexane, Et₂O, 4 deg C, 48 h, 2.) -78 deg C -> RT, then reflux, 5 min

With palladium diacetate; n-butyllithium; lithium tert-butyl hydroperoxide; In acetic acid; trifluoroacetic acid;