Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)

Base Information

• Chemical Name: Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)
• CAS No.: 223522-39-2
• Molecular Formula: C₄₆H₅₅FeN₇O
• Molecular Weight: 777.836
• Mol file: 223522-39-2.mol

Synonyms:Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)

Chemical Property of Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)

There total 2 articles about Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

1-methyl-1H-imidazole (616-47-7) + C42H49FeN6O2 → Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole) (223522-39-2) + octaethylporphyrin iron(II) nitrosyl (55917-58-3)

Guidance literature:

In dichloromethane; at -45 ℃; for 1h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1039/c5dt03074a

Reference yield:

1-methyl-1H-imidazole (616-47-7) + chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) complex (28755-93-3) + Nitrosobenzene (586-96-9) → Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole) (223522-39-2)

Guidance literature:

With NaBH₄; In tetrahydrofuran; Ar-atmosphere; addn. of NaBH4 to Fe(OEP)Cl, then addn. of 1-MeIm, then addn. 1.2 equiv. of PhNO; recrystn. (toluene/pentane);

DOI:10.1021/ja9832820

upstream raw materials:

1-methyl-1H-imidazole

chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N'',N''')iron(III) complex

Nitrosobenzene

Refernces

• 1、 Godbout, Nathalie,Sanders, Lori K.,Salzmann, Renzo,Havlin, Robert H.,Wojdelski, Mark,Oldfield, Eric. "Solid-state NMR, Moessbauer, crystallographic, and density functional theory investigation of Fe-O2 and Fe-O2 analogue metalloporphyrins and metalloproteins". . p. 3829 - 3844. Retrieved 2007/10/03.