(E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Base Information

• Chemical Name: (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene
• CAS No.: 1342884-61-0
• Molecular Formula: C₂₅H₂₄F₃IN₂O₂
• Molecular Weight: 568.377
• Mol file: 1342884-61-0.mol

Synonyms:(E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Chemical Property of (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

There total 3 articles about (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.5%

p-Iodophenol (540-38-5) + (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-55-2) → (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-61-0)

Guidance literature:

With potassium iodide; potassium hydroxide; In dimethyl sulfoxide; acetone; for 24h; Reflux;

DOI:10.1016/j.polymer.2011.09.026

Reference yield:

4-trifluoromethylphenylamine (455-14-1) → (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-61-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: hydrogenchloride; sodium nitrite / water / 0.25 h / 0 - 5 °C

1.2: Cooling with ice

2.1: potassium carbonate / acetone / 24 h / Reflux

3.1: potassium iodide; potassium hydroxide / dimethyl sulfoxide; acetone / 24 h / Reflux

With hydrogenchloride; potassium carbonate; potassium iodide; potassium hydroxide; sodium nitrite; In water; dimethyl sulfoxide; acetone;

DOI:10.1016/j.polymer.2011.09.026

Reference yield:

(E)-4-((4-(trifluoromethyl)phenyl)diazenyl)phenol (4316-21-6) → (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-61-0)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / acetone / 24 h / Reflux

2: potassium iodide; potassium hydroxide / dimethyl sulfoxide; acetone / 24 h / Reflux

With potassium carbonate; potassium iodide; potassium hydroxide; In dimethyl sulfoxide; acetone;

DOI:10.1016/j.polymer.2011.09.026

upstream raw materials:

p-Iodophenol

(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

4-trifluoromethylphenylamine

(E)-4-((4-(trifluoromethyl)phenyl)diazenyl)phenol

Downstream raw materials:

(E)-1-(4-(6-(4-ethynylphenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

(E)-1-(4-(trifluoromethyl)phenyl)-2-(4-(6-(4-((trimethylsilyl)ethynyl)phenoxy)hexyloxy)phenyl)diazene