(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Base Information

• Chemical Name: (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene
• CAS No.: 1342884-55-2
• Molecular Formula: C₁₉H₂₀BrF₃N₂O
• Molecular Weight: 429.28
• Mol file: 1342884-55-2.mol

Synonyms:(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Chemical Property of (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

There total 2 articles about (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.8%

1 ,6-dibromohexane (629-03-8) + (E)-4-((4-(trifluoromethyl)phenyl)diazenyl)phenol (4316-21-6) → (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-55-2)

Guidance literature:

With potassium carbonate; In acetone; for 24h; Reflux;

DOI:10.1016/j.polymer.2011.09.026

Reference yield:

4-trifluoromethylphenylamine (455-14-1) → (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-55-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydrogenchloride; sodium nitrite / water / 0.25 h / 0 - 5 °C

1.2: Cooling with ice

2.1: potassium carbonate / acetone / 24 h / Reflux

With hydrogenchloride; potassium carbonate; sodium nitrite; In water; acetone;

DOI:10.1016/j.polymer.2011.09.026

Reference yield: 80.5%

p-Iodophenol (540-38-5) + (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-55-2) → (E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene (1342884-61-0)

Guidance literature:

With potassium iodide; potassium hydroxide; In dimethyl sulfoxide; acetone; for 24h; Reflux;

DOI:10.1016/j.polymer.2011.09.026

upstream raw materials:

1 ,6-dibromohexane

(E)-4-((4-(trifluoromethyl)phenyl)diazenyl)phenol

4-trifluoromethylphenylamine

Downstream raw materials:

(E)-1-(4-(trifluoromethyl)phenyl)-2-(4-(6-(4-((trimethylsilyl)ethynyl)phenoxy)hexyloxy)phenyl)diazene

(E)-1-(4-(6-(4-ethynylphenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene

(E)-1-(4-(6-(4-iodophenoxy)hexyloxy)phenyl)-2-(4-(trifluoromethyl)phenyl)diazene