cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin

Base Information

• Chemical Name: cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin
• CAS No.: 142781-57-5
• Molecular Formula: C₄₄H₃₀N₈O₄
• Molecular Weight: 734.773
• Mol file: 142781-57-5.mol

Synonyms:cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin

Chemical Property of cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin

There total 3 articles about cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8) → tetrakis(4-aminophenyl)porphyrin (22112-84-1) + <5-(4-nitrophenyl)-10,15,20-tris(4-aminophenyl)>porphyrin (142781-58-6) + cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin (142781-57-5) + 5-(4-aminophenyl)-10,15,20-tris(4-nitrophenyl)porphyrin (142781-55-3)

Guidance literature:

With hydrogenchloride; tin(ll) chloride; at 75 ℃; for 24h; Further byproducts given. Title compound not separated from byproducts;

DOI:10.1021/ja00043a055

Reference yield: 30.0%

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8) → <5-(4-nitrophenyl)-10,15,20-tris(4-aminophenyl)>porphyrin (142781-58-6) + trans-<5,15-bis(4-aminophenyl)-10,20-bis(4-nitrophenyl)>porphyrin (142781-56-4) + cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin (142781-57-5) + 5-(4-aminophenyl)-10,15,20-tris(4-nitrophenyl)porphyrin (142781-55-3)

Guidance literature:

With hydrogenchloride; tin(ll) chloride; at 75 ℃; for 24h; Further byproducts given;

DOI:10.1021/ja00043a055

Reference yield:

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8) → tetrakis(4-aminophenyl)porphyrin (22112-84-1) + trans-<5,15-bis(4-aminophenyl)-10,20-bis(4-nitrophenyl)>porphyrin (142781-56-4) + cis-<5,10-bis(4-aminophenyl)-15,20-bis(4-nitrophenyl)>porphyrin (142781-57-5) + 5-(4-aminophenyl)-10,15,20-tris(4-nitrophenyl)porphyrin (142781-55-3)

Guidance literature:

With hydrogenchloride; sodium hydroxide; tin(ll) chloride; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) from 75 to 80 deg C, 24 h, 2.) 1 h;

DOI:10.1002/jccs.199700005

upstream raw materials:

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin

Refernces

• 1、 Suslick, Kenneth S.,Chen, Chin-Ti,Meredith, Gerald R.,Cheng, Lap-Tak. "Push-Pull Porphyrins as Nonlinear Optical Materials". . p. 6928 - 6930. Retrieved 2007/10/02.