Technology Process of C25H26OSi
There total 4 articles about C25H26OSi which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
20% palladium hydroxide on charcoal; hydrogen;
In
ethyl acetate;
at 20 ℃;
for 11h;
under 760.051 Torr;
optical yield given as %ee;
diastereoselective reaction;
DOI:10.1021/ja208621x
- Guidance literature:
-
Multi-step reaction with 4 steps
1: tetrahydrofuran; diethyl ether / 0 - 20 °C
2: diethyl ether / 0 - 35 °C
3: allyl(cyclopentadiene)palladium(II); C38H42NO2P / toluene / 20 - 30 °C
4: 20% palladium hydroxide on charcoal; hydrogen / ethyl acetate / 11 h / 20 °C / 760.05 Torr
With
allyl(cyclopentadiene)palladium(II); 20% palladium hydroxide on charcoal; C38H42NO2P; hydrogen;
In
tetrahydrofuran; diethyl ether; ethyl acetate; toluene;
DOI:10.1021/ja208621x
- Guidance literature:
-
Multi-step reaction with 3 steps
1: diethyl ether / 0 - 35 °C
2: allyl(cyclopentadiene)palladium(II); C38H42NO2P / toluene / 20 - 30 °C
3: 20% palladium hydroxide on charcoal; hydrogen / ethyl acetate / 11 h / 20 °C / 760.05 Torr
With
allyl(cyclopentadiene)palladium(II); 20% palladium hydroxide on charcoal; C38H42NO2P; hydrogen;
In
diethyl ether; ethyl acetate; toluene;
DOI:10.1021/ja208621x