magnesium dibutanolate

Base Information

• Chemical Name: magnesium dibutanolate
• CAS No.: 15921-15-0
• Molecular Formula: C4H10 O . 1/2 Mg
• Molecular Weight: 98.4278
• Mol file: 15921-15-0.mol

Synonyms:1-Butanol,magnesium salt (9CI); Butyl alcohol, magnesium salt (8CI); Magnesium butoxide(7CI); Dibutoxymagnesium; Magnesium dibutoxide

Chemical Property of magnesium dibutanolate

Chemical Property:

• Vapor Pressure: 8.52mmHg at 25°C
• Boiling Point: 117.7°Cat760mmHg
• Flash Point: 35°C
• PSA: 46.12000
• Density: g/cm³
• LogP: 2.43400

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of magnesium dibutanolate

There total 11 articles about magnesium dibutanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

magnesium (7439-95-4) + butan-1-ol (71-36-3) → magnesium di-n-butanolate (15921-15-0)

Guidance literature:

With iodine; for 2h; Reflux; Inert atmosphere;

DOI:10.1039/c4dt03207a

Reference yield:

Mg(n-PrOH)(1+) (35754-82-6) + butan-1-ol (71-36-3) → propan-1-ol (71-23-8) + Mg(1+)(n-BuOH) (15921-15-0)

Guidance literature:

Rate constant; Equilibrium constant; Thermodynamic data; Ambient temperature; gas phase reaction, ΔG_exch;

DOI:10.1021/ja00220a020

Reference yield:

Mg(i-PrOH)(1+) (15571-48-9) + butan-1-ol (71-36-3) → Mg(1+)(n-BuOH) (15921-15-0) + isopropyl alcohol (67-63-0,8013-70-5)

Guidance literature:

Rate constant; Equilibrium constant; Thermodynamic data; Ambient temperature; gas phase reaction, ΔG_exch;

DOI:10.1021/ja00220a020

upstream raw materials:

allyl n-butyl ether

tetrahydrofuran

butan-1-ol

magnesium methanolate

Downstream raw materials:

Mg⁽¹⁺⁾-tetrahydrofuran

butan-1-ol

Mg(i-PrOH)⁽¹⁺⁾

benzyl 1-butyl ether

Refernces

• 1、 Machacek, Miloslav,Demuth, Jiri,Cermak, Pavel,Vavreckova, Magda,Hruba, Lenka,Jedlickova, Adela,Kubat, Pavel,Simunek, Tomas,Novakova, Veronika,Zimcik, Petr. "Tetra(3,4-pyrido)porphyrazines Caught in the Cationic Cage: Toward Nanomolar Active Photosensitizers". . p. 9443 - 9456. Retrieved 2016.
• 2、 Colomban, Cdric,Kudrik, Evgeny V.,Tyurin, Dmitry V.,Albrieux, Florian,Nefedov, Sergei E.,Afanasiev, Pavel,Sorokin, Alexander B.. "Synthesis and characterization of μ-nitrido, μ-carbido and μ-oxo dimers of iron octapropylporphyrazine". . p. 2240 - 2251. Retrieved 2015.
• 3、 Klein, Thomas,Ziegler, Thomas. "First example of an octa-glycoconjugated magnesium(II)porphyrazine". . p. 495 - 497. Retrieved 2016.
• 4、 Koak, Didar,Gonca, Ergün. "Synthesis, structural and spectral properties of novel octakis(3,5-bis- trifluoromethyl-benzylthio) substituted porphyrazine derivatives". . p. 1322 - 1326. Retrieved 2010.
• 5、 Goslinski, Tomasz,Koczorowski, Tomasz,Szczolko, Wojciech,Teubert, Anna. "Sulfanyl porphyrazines with morpholinylethyl periphery—synthesis, electrochemistry, and photocatalytic studies after deposition on titanium(Iv) oxide p25 nanoparticles". . . Retrieved 2021/05/28.
• 6、 Chen, Rui,Yang, Changjun,Zhang, Quanquan,Zhang, Bingguang,Deng, Kejian. "Visible-light-driven selective oxidation of glucose in water with H-ZSM-5 zeolite supported biomimetic photocatalyst". . p. 297 - 305. Retrieved 2019/05/24.