MAGNESIUM METHOXIDE

Base Information

• Chemical Name: MAGNESIUM METHOXIDE
• CAS No.: 109-88-6
• Molecular Formula: C₂H₆MgO₂
• Molecular Weight: 86.3734
• Mol file: 109-88-6.mol

Synonyms:Magnesiummethoxide (6CI,7CI);Methanol, magnesium salt (8CI,9CI);Bis(methoxy)magnesium;Dimethoxymagnesium;Magnesium dimethoxide;Magnesium methylate;

Chemical Property of MAGNESIUM METHOXIDE

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 265mmHg at 25°C
• Refractive Index: n20/D 1.3381
• Boiling Point: 48.1 °C at 760 mmHg
• Flash Point: 11.1 °C
• PSA: 18.46000
• Density: 0.816 g/mL at 25 °C
• LogP: 0.19420
• Sensitive.: Moisture Sensitive
• Water Solubility.: Decomposes in water.

Purity/Quality:

99.5%,99%, ^*data from raw suppliers

Magnesium methoxide solution 6-10wt. % in methanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, T
• Hazard Codes: F,T
• Statements: 11-23/24/25-39/23/24/25-36/38
• Safety Statements: 16-36/37-45-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: The use of magnesium methoxide for the deprotection of alkyl esters is described. This mild reagent provides a good method to cleave esters efficiently and more importantly, allows for effective differentiation between two different esters. Dimethyl carbonate is synthesized directly from carbon dioxide and methanol in the presence of magnesium methoxide. 20 mol% DEA additions to magnesium methoxide showed enhanced stability such that a time-dependent change in the sol was not observed in air. Also enhanced the crystallization process.

Technology Process of MAGNESIUM METHOXIDE

There total 6 articles about MAGNESIUM METHOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methanol (67-56-1) → magnesium methanolate (109-88-6,16436-83-2,16436-85-4)

Guidance literature:

With magnesium; at 64 ℃; for 12h;

Reference yield:

methanol (67-56-1) + magnesium (7439-95-4) → magnesium methanolate (109-88-6,16436-83-2,16436-85-4)

Guidance literature:

at 40 ℃;

Reference yield:

sodium methylate (124-41-4) → magnesium methanolate (109-88-6,16436-83-2,16436-85-4)

Guidance literature:

With magnesium chloride; In hexane; at 45 ℃; for 10h; Inert atmosphere;

upstream raw materials:

methanol

magnesium

magnesium ethylate

sodium methylate

Downstream raw materials:

methyl 4-hydroxylbenzoate

2,4-Dioxo-6-imino-1,3-diaza-hexahydrobenzol

cholesteryl methyl ether

methyl magnesium carbonate

Refernces

• 1、 Guo, Qianqian,Englert, Ulli. "An Acetylacetonate or a Pyrazole? Both! 3-(3,5-Dimethyl-pyrazol-4-yl)pentane-2,4-dione as a Ditopic Ligand". . p. 5127 - 5135. Retrieved 2016.
• 2、 Lin, Ji-Mao,Li, Hui-Hui,Zhou, Ai-Min. "Synthesis of benzyl/allyl alkyl ethers from corresponding magnesium alkoxides". . p. 5159 - 5160. Retrieved 1996.
• 3、 -. "Alkoxy metal powder as well as preparation method and application thereof". Paragraph 0079-0080. . Retrieved 2019/12/02.
• 4、 Kuznetsov, Denis A.,Konev, Dmitry V.,Sokolov, Sergey A.,Fedyanin, Ivan V.. "Cobalt Oxide Materials for Oxygen Evolution Catalysis via Single-Source Precursor Chemistry". . p. 13890 - 13896. Retrieved 2018/09/14.