p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

Base Information

Chemical Name:p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside
CAS No.:905267-00-7
Molecular Formula:C₃₀H₃₀Cl₃NO₆S
Molecular Weight:638.996
Hs Code.:

Synonyms:p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

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Chemical Property of p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

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Technology Process of p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

There total 9 articles about p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: (2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-2-phenyl-6-p-tolylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ylamine; compound with sulfuric acid

: 17341-93-4
2,2,2-Trichloroethyl chloroformate

: 905267-00-7
p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

Guidance literature:: With sodium hydrogencarbonate; In tetrahydrofuran; water; for 1h;
DOI:10.1016/j.carres.2006.01.007

Reference yield: 90.0%

: 100-52-7
benzaldehyde

: 929040-52-8
p-tolyl N-2,2,2-trichloroethyloxycarbonyl-2-amino-4,6-O-benzylidene-2-deoxy-1-thio-β-D-glucopyranoside

: 905267-00-7
p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

Guidance literature:: p-tolyl N-2,2,2-trichloroethyloxycarbonyl-2-amino-4,6-O-benzylidene-2-deoxy-1-thio-β-D-glucopyranoside; With triethylsilyl trifluoromethyl sulfonate; In tetrahydrofuran; toluene; at -20 ℃; for 0.75h; Inert atmosphere;

benzaldehyde; With triethylsilane; In tetrahydrofuran; toluene; at -20 ℃; for 2h; Inert atmosphere;

Reference yield: 83.0%

: C₂₆H₃₂Cl₃NO₆SSi

: 100-52-7
benzaldehyde

: 905267-00-7
p-tolyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside

Guidance literature:: C₂₆H₃₂Cl₃NO₆SSi; benzaldehyde; In dichloromethane; at 20 ℃; for 1h; Molecular sieve;

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -30 ℃; for 2h; Temperature;
DOI:10.1039/d0ob00252f