Nickel-63(II) chloride

Base Information

• Chemical Name: Nickel-63(II) chloride
• CAS No.: 7718-54-9
• Molecular Formula: NiCl2
• Molecular Weight: 129.596
• Hs Code.: 28273500
• UNII: 696BNE976J
• DSSTox Substance ID: DTXSID7040316
• Nikkaji Number: J3.106B
• Mol file: 7718-54-9.mol

Synonyms:63-Nickel chloride;63-Nickel dichloride;Nickel-63(II) chloride;Nickel chloride (63NiCl2);DTXSID7040316;83864-14-6;Cl2Ni;Cl2-Ni;NICKEL CHLORIDE [MI];NICKEL CHLORIDE [HSDB];Tox21_302175;s12327;NCGC00255504-01;CAS-7718-54-9;N0850;N0851

Chemical Property of Nickel-63(II) chloride

Chemical Property:

• Appearance/Colour: Golden yellow crystalline powder
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 1001 °C
• Boiling Point: Sublimes at 973oC; deliquesces
• PSA: 0.00000
• Density: 3.55 g/cm³
• LogP: 1.37900
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: H2O: soluble
• Water Solubility.: slightly soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 127.873047
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Nickel(II) Chloride Anhydrous ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N,Xi
• Statements: 45-25-36/38-43-50-50/53-22-52/53-68-51/53-48/23-42/43-20/22-61-49-38-23/25
• Safety Statements: 53-26-36/37-45-61-37-29-24-23-60

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Ni+2]
• Description: Nickel chloride is a brown or green colored solid. Most nickel chloride is used for electroplating and nickel plating, used to prepare various nickel salts and nickel catalysts; . During electroplating, it accelerates the dissolution of anode metal nickel, while acting to increase the electrolyte level of the solution. Nickel chloride can be used as catalyst for organic synthesis (e.g. pyrazolophthalazinyl spirooxindoles), to synthesize nickel nanoparticles as a reductant, and to prepare nickel coordination compounds, and and in industrial gas masks to protect from ammonia. It can also be used as an NH3 absorbent in gas masks and as a source of nickel ion for cell culture and toxicological studies. Nickel chloride, NiCl2, is a water-soluble salt used in a variety of industries. It is typically produced and used either as an anhydrous salt or as a hydrate: nickel chloride hexahydrate as well as nickel chloride dihydrate. Nickel chloride is very rarely found in nature, and is produced via extraction from nickelcontaining ores via treatment with hydrochloric acid.
• Physical properties: The anhydrous salt forms yellow crystal scales; deliquesces; density 3.55 g/cm3; melts at 1,001°C; sublimes at 973°C; highly soluble in water, 64 g/100mL at 20°C; soluble in alcohol.The hexahydrate forms green monoclinic crystals; deliquesces; extremely soluble in water, 254 g/100mL at 20°C, and about 600 g/100 ml at 100°C; also very soluble in alcohol.
• Uses: Nickel chloride (NiCl2) is used for electroplating nickel onto the surfaces of other metals and as a chemical reagent in laboratories. Nickel chloride solutions are used for electroplating nickel onto other metal items.It also is used to prepare various nickel salts and nickel catalysts; and in industrial gas masks to protect from ammonia. Nickel chloride is used for nickel plating cast zinc, as an agent in electrolytic refining of nickel, as a chemical intermediate for nickel catalysts and complex nickel salts, as an absorber of ammonia gas in industrial gas masks, as a catalyst in diarylamine and silicon tetrachloride production, as an agent in electrodeless plating of nickel, as an agent in tin–nickel alloy plating, and as a fungicide for control of rust and rustlike disease. However, workers exposed to different forms of nickel have an elevated risk of lung cancer. Besides, Ni and its compounds (particularly insoluble compounds of nickel) have been reported to be potent carcinogens and toxic agents in humans and experimental animals. Therefore, Ni compounds are considered to be an industrial/occupational health hazard.

Technology Process of Nickel-63(II) chloride

There total 3 articles about Nickel-63(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + nickel (7440-02-0) → nickel(II) chloride (7718-54-9,83864-14-6)

Guidance literature:

In water; Dissoln. of Ni wire in aq. HCl at about 50°C using a piece of Pt in contact with the Ni (acting as cathode for better soln. of Ni).; Placement of NiCl2 in a quartz boat, vaporisation by heating to about 600°C, seeding of vapor in about 4 atm of Ar, expanding through nozzle (250μm hole).;

DOI:10.1016/0009-2614(88)87488-8

Reference yield:

nickel (7440-02-0) + silver(I) chloride → nickel(II) chloride (7718-54-9,83864-14-6)

Guidance literature:

In neat (no solvent, solid phase); mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2 or Ar);

DOI:10.1016/0009-2614(91)90088-Q

Reference yield:

→ nickel(II) chloride (7718-54-9,83864-14-6)

Guidance literature:

upstream raw materials:

nickel

hydrogenchloride

Downstream raw materials:

(Z)-7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester

4-{5-(4-cyanophenyl)-2-methylbenzyl}-5-methoxy-2-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one

Refernces

• 1、 Beattle, Ian R.,Spicer, Mark D.,Young, Nigel A.. "Interatomic distances for some first row transition element dichlorides isolated in cryogenic matrices using x-ray absorption fine structure spectroscopy". . p. 8700 - 8705. Retrieved 2007/10/02.