CAS No.7718-54-9,Nickel chloride Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	7718-54-9
Name:	Nickel chloride
Article Data:	4

Formula:	NiCl₂
Molecular Weight:	129.596
Synonyms:	NSC254532;Nickel dichloride;Nickel dichloride (NiCl2);Nickel(2+) chloride;Nickel(II) chloride;Nickelous chloride;Nickelchloride (NiCl2);
EINECS:	231-743-0
Density:	3.55 g/cm³
Melting Point:	1001 °C
Boiling Point:	Sublimes at 973oC; deliquesces
Solubility:	slightly soluble in water
Appearance:	Golden yellow crystalline powder
Hazard Symbols:	T,N
Risk Codes:	45-25-36/38-43-50-50/53-22-52/53
Safety:	53-26-36/37-45-61-37-29-24
Transport Information:	UN 3288 6.1/PG 3
PSA:	0.00000
LogP:	1.37900

Synthetic route

: 7440-02-0
nickel

: silver(I) chloride

: 7718-54-9
nickel(II) chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2 or Ar);

: 7647-01-0
hydrogenchloride

: 7440-02-0
nickel

: 7718-54-9
nickel(II) chloride

Conditions

Conditions	Yield
In water Dissoln. of Ni wire in aq. HCl at about 50°C using a piece of Pt in contact with the Ni (acting as cathode for better soln. of Ni).; Placement of NiCl2 in a quartz boat, vaporisation by heating to about 600°C, seeding of vapor in about 4 atm of Ar, expanding through nozzle (250μm hole).;
In neat (no solvent) isolation in N2 or CH4 solid matrix;

: 802907-39-7
7-((R)-2-hydroxymethyl-6-oxo-piperidin-1-yl)-hept-5-ynoic acid methyl ester

: 7718-54-9
nickel(II) chloride

: 7-((R)-2-hydroxymethyl-6-oxo-piperidin-1-yl)-hept-5-enoic acid methyl ester

Conditions

Conditions	Yield
With sodium borohydrid In ethanol; ethylenediamine	16.7 mg (38%)

: 623-03-0
4-Cyanochlorobenzene

: 258885-52-8
4-(5-bromo-2-methylbenzyl)-5-methoxy-2-methyl-2,4-dihydro-3H,1-2,4-triazol-3-one

: 7718-54-9
nickel(II) chloride

: 7440-66-6
zinc

: 258885-71-1
4-{5-(4-cyanophenyl)-2-methylbenzyl}-5-methoxy-2-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydrogencarbonate; triphenylphosphine In pyridine; water; ethyl acetate

...Expand

[(4-methoxybenzenesulfonyl)-2-oxo-athyl)-amino]acetic acid t-butyl ester: [(4-methoxybenzenesulfonyl)-2-oxo-athyl)-amino]acetic acid t-butyl ester

: 42599-24-6
E-styryl iodide

: 10049-05-5
chromium (II) chloride

: 7718-54-9
nickel(II) chloride

: (+)-(E)-[(2-hydroxy-4-phenyl-but-3-enyl)-(4-methoxybenzenesulphonyl)-amino]-acetic acid t-butyl ester

Conditions

Conditions	Yield
In N-methyl-acetamide

...Expand

: 593-60-2
Vinyl bromide

: 154-87-0
thiamine diphosphate

: 7718-54-9
nickel(II) chloride

: 138526-69-9
3,4,5-trifluoro-1-bromobenzene

: 3,4,5-Trifluorovinylbenzene

Conditions

Conditions	Yield
With n-butyllithium; zinc dibromide In tetrahydrofuran

...Expand

: 620-73-5
phenyl chloroacetate

: 106-43-4
para-chlorotoluene

: 7718-54-9
nickel(II) chloride

: 127783-74-8
4-acetoxy-4’-methylbiphenyl

Conditions

Conditions	Yield
With sodium iodide; zinc In N-methyl-acetamide; chloroform

...Expand

: 697802-45-2
7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester

: 7718-54-9
nickel(II) chloride

: 697802-47-4
(Z)-7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester

Conditions

Conditions	Yield
With sodium borohydrid In ethanol; ethyl acetate; ethylenediamine	65 mg (43%)

: 697802-67-8
7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester

: 7718-54-9
nickel(II) chloride

: 697802-69-0
(Z)-7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester

Conditions

Conditions	Yield
With sodium borohydrid In ethanol; ethylenediamine	28 mg (70%)
With sodium borohydrid In ethanol; ethylenediamine	28 mg (70%)

Raw Materials

7647-01-0

7440-02-0

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Chemistry

IUPAC Name: Dichloronickel
Synonyms: Nickel (II) chloride ; Nickel (II) chloride (1:2) ; Nickel(2+) dichloride ; Nickel(II) chloride (1:2)
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Nickel Salts;NickelMetal and Ceramic Science;Salts;Crystal Grade Inorganics;Metal and Ceramic Science
Molecular Formula of Nickel chloride (CAS NO.7718-54-9) : NiCl₂
Molecular Weight of Nickel chloride (CAS NO.7718-54-9) : 129.60
Molecular Structure of Nickel chloride (CAS NO.7718-54-9) :
CAS NO: 7718-54-9
EINECS : 231-743-0
Mol File: 7718-54-9.mol
Melting point: 1001 °C
Boiling Point: 987°C
Density : 3.55 g/mL at 25 °C(lit.)
Solubility: H₂O: soluble
Water Solubility: slightly soluble
Sensitive: Hygroscopic
Merck : 14,6505
Stability: Stable. Incompatible with peroxides.
Appearance:Golden yellow crystalline powder

Uses

Nickel chloride (CAS NO.7718-54-9) is used for nickel, manufacture of sympathetic ink and Ammonia absorber.

Production

Preparation Products Nickel(II) chloride hexahydrate-->(4-(4-[BIS(4-FLUOROPHENYL)METHYL]PIPERAZIN-1-YL)PHENYL)METHANOL-->Nickel(II) nitrate hexahydrate-->(1,3-DIMETHYL-1H-PYRAZOL-5-YL)METHYLAMINE-->2-(1,3-Dimethyl-1H-pyrazol-5-yl)ethanamine ,97%-->(1,5-DIMETHYL-1H-PYRAZOL-3-YL)METHYLAMINE-->Nickel dibutyldithiocarbamate
Raw materials Hydrochloric acid-->Sulfuric acid -->Nitric acid-->Sodium carbonate-->Nickel-->Nickel sulfate -->Nickel carbonate

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	11mg/kg (11mg/kg)		Toxicology. Vol. 64, Pg. 19, 1990.
mouse	LD50	intravenous	20mg/kg (20mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
mouse	LD50	oral	369mg/kg (369mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rabbit	LD50	intramuscular	27mg/kg (27mg/kg)		Journal of Pharmacology and Experimental Therapeutics. Vol. 87, Pg. 119, 1946.
rat	LD50	intraperitoneal	20597ug/kg (20.597mg/kg)		Toxicology. Vol. 35, Pg. 47, 1985.
rat	LD50	intravenous	68100ug/kg (68.1mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat	LD50	oral	681mg/kg (681mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.

Safety Profile

Hazard Codes Toxic T Dangerous N, Irritant Xi
Risk Statements 45-25-36/38-43-50/53-22-52
R22:Harmful if swallowed.
R25 :Toxic if swallowed.
R45:May cause cancer.
R43:May cause sensitization by skin contact.
R36/38:Irritating to eyes and skin.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52:Harmful to aquatic organisms.
Safety Statements 53-26-36/37-45-61-29-24
S53:Avoid exposure - obtain special instructions before use.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S29:Do not empty into drains.
S24:Avoid contact with skin.
RIDADR UN 3288 6.1/PG 3
WGK Germany 3
RTECS QR6475000
F 3
HazardClass 6.1(b)
PackingGroup III

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen.