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| CAS No.: | 7718-54-9 |
|---|---|
| Name: | Nickel chloride |
| Molecular Structure: | |
|
|
|
| Formula: | NiCl2 |
| Molecular Weight: | 129.596 |
| Synonyms: | NSC254532;Nickel dichloride;Nickel dichloride (NiCl2);Nickel(2+) chloride;Nickel(II) chloride;Nickelous chloride;Nickelchloride (NiCl2); |
| EINECS: | 231-743-0 |
| Density: | 3.55 g/cm3 |
| Melting Point: | 1001 °C |
| Boiling Point: | Sublimes at 973oC; deliquesces |
| Solubility: | slightly soluble in water |
| Appearance: | Golden yellow crystalline powder |
| Hazard Symbols: |
 T, N
|
| Risk Codes: | 45-25-36/38-43-50-50/53-22-52/53 |
| Safety: | 53-26-36/37-45-61-37-29-24 |
| Transport Information: | UN 3288 6.1/PG 3 |
| PSA: | 0.00000 |
| LogP: | 1.37900 |
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| Conditions | Yield |
|---|---|
| In neat (no solvent, solid phase) mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2 or Ar); |
| Conditions | Yield |
|---|---|
| In water Dissoln. of Ni wire in aq. HCl at about 50°C using a piece of Pt in contact with the Ni (acting as cathode for better soln. of Ni).; Placement of NiCl2 in a quartz boat, vaporisation by heating to about 600°C, seeding of vapor in about 4 atm of Ar, expanding through nozzle (250μm hole).; | |
| In neat (no solvent) isolation in N2 or CH4 solid matrix; |
- 802907-39-7
7-((R)-2-hydroxymethyl-6-oxo-piperidin-1-yl)-hept-5-ynoic acid methyl ester
- 7718-54-9
nickel(II) chloride
| Conditions | Yield |
|---|---|
| With sodium borohydrid In ethanol; ethylenediamine | 16.7 mg (38%) |
- 623-03-0
4-Cyanochlorobenzene
- 258885-52-8
4-(5-bromo-2-methylbenzyl)-5-methoxy-2-methyl-2,4-dihydro-3H,1-2,4-triazol-3-one
- 7718-54-9
nickel(II) chloride
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zinc
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4-{5-(4-cyanophenyl)-2-methylbenzyl}-5-methoxy-2-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium hydrogencarbonate; triphenylphosphine In pyridine; water; ethyl acetate |
| Conditions | Yield |
|---|---|
| In N-methyl-acetamide |
- 593-60-2
Vinyl bromide
- 154-87-0
thiamine diphosphate
- 7718-54-9
nickel(II) chloride
- 138526-69-9
3,4,5-trifluoro-1-bromobenzene
| Conditions | Yield |
|---|---|
| With n-butyllithium; zinc dibromide In tetrahydrofuran |
- 620-73-5
phenyl chloroacetate
- 106-43-4
para-chlorotoluene
- 7718-54-9
nickel(II) chloride
- 127783-74-8
4-acetoxy-4’-methylbiphenyl
| Conditions | Yield |
|---|---|
| With sodium iodide; zinc In N-methyl-acetamide; chloroform |
- 697802-45-2
7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester
- 7718-54-9
nickel(II) chloride
- 697802-47-4
(Z)-7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester
| Conditions | Yield |
|---|---|
| With sodium borohydrid In ethanol; ethyl acetate; ethylenediamine | 65 mg (43%) |
- 697802-67-8
7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester
- 7718-54-9
nickel(II) chloride
- 697802-69-0
(Z)-7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester
| Conditions | Yield |
|---|---|
| With sodium borohydrid In ethanol; ethylenediamine | 28 mg (70%) |
| With sodium borohydrid In ethanol; ethylenediamine | 28 mg (70%) |
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- Total:27 Page 1 of 1 1
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Chemistry
IUPAC Name: Dichloronickel
Synonyms: Nickel (II) chloride ; Nickel (II) chloride (1:2) ; Nickel(2+) dichloride ; Nickel(II) chloride (1:2)
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Nickel Salts;NickelMetal and Ceramic Science;Salts;Crystal Grade Inorganics;Metal and Ceramic Science
Molecular Formula of Nickel chloride (CAS NO.7718-54-9) : NiCl2
Molecular Weight of Nickel chloride (CAS NO.7718-54-9) : 129.60
Molecular Structure of Nickel chloride (CAS NO.7718-54-9) : 
CAS NO: 7718-54-9
EINECS : 231-743-0
Mol File: 7718-54-9.mol
Melting point: 1001 °C
Boiling Point: 987°C
Density : 3.55 g/mL at 25 °C(lit.)
Solubility: H2O: soluble
Water Solubility: slightly soluble
Sensitive: Hygroscopic
Merck : 14,6505
Stability: Stable. Incompatible with peroxides.
Appearance:Golden yellow crystalline powder
Uses
Nickel chloride (CAS NO.7718-54-9) is used for nickel, manufacture of sympathetic ink and Ammonia absorber.
Production
Preparation Products Nickel(II) chloride hexahydrate-->(4-(4-[BIS(4-FLUOROPHENYL)METHYL]PIPERAZIN-1-YL)PHENYL)METHANOL-->Nickel(II) nitrate hexahydrate-->(1,3-DIMETHYL-1H-PYRAZOL-5-YL)METHYLAMINE-->2-(1,3-Dimethyl-1H-pyrazol-5-yl)ethanamine ,97%-->(1,5-DIMETHYL-1H-PYRAZOL-3-YL)METHYLAMINE-->Nickel dibutyldithiocarbamate
Raw materials Hydrochloric acid-->Sulfuric acid -->Nitric acid-->Sodium carbonate-->Nickel-->Nickel sulfate -->Nickel carbonate
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 11mg/kg (11mg/kg) | Toxicology. Vol. 64, Pg. 19, 1990. | |
| mouse | LD50 | intravenous | 20mg/kg (20mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. |
| mouse | LD50 | oral | 369mg/kg (369mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. |
| rabbit | LD50 | intramuscular | 27mg/kg (27mg/kg) | Journal of Pharmacology and Experimental Therapeutics. Vol. 87, Pg. 119, 1946. | |
| rat | LD50 | intraperitoneal | 20597ug/kg (20.597mg/kg) | Toxicology. Vol. 35, Pg. 47, 1985. | |
| rat | LD50 | intravenous | 68100ug/kg (68.1mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. |
| rat | LD50 | oral | 681mg/kg (681mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. |
Safety Profile
Hazard Codes 
T
N,
Xi
Risk Statements 45-25-36/38-43-50/53-22-52
R22:Harmful if swallowed.
R25 :Toxic if swallowed.
R45:May cause cancer.
R43:May cause sensitization by skin contact.
R36/38:Irritating to eyes and skin.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52:Harmful to aquatic organisms.
Safety Statements 53-26-36/37-45-61-29-24
S53:Avoid exposure - obtain special instructions before use.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S29:Do not empty into drains.
S24:Avoid contact with skin.
RIDADR UN 3288 6.1/PG 3
WGK Germany 3
RTECS QR6475000
F 3
HazardClass 6.1(b)
PackingGroup III
Specification
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen.