[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

Base Information

Chemical Name:[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)
CAS No.:1312229-53-0
Molecular Formula:C₈₄H₁₂₄N₄Zn
Molecular Weight:1255.33
Hs Code.:

Synonyms:[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

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Chemical Property of [5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

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Technology Process of [5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

There total 7 articles about [5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5,15-bis(3,5-di-n-tridecylphenyl)-porphyrin

: 1312229-53-0
[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

Guidance literature:: With zinc(II) acetate dihydrate; In methanol; chloroform; at 20 ℃; Darkness;
DOI:10.1021/cm2004648

Reference yield:

: 1312229-45-0
1-bromo-3,5-di-n-tridecenyl-benzene

: 1312229-53-0
[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

Guidance literature:: Multi-step reaction with 4 steps

1.1: palladium on activated charcoal / tetrahydrofuran / 20 h / 22 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -60 °C / Inert atmosphere

2.2: 2 h / 20 °C / Inert atmosphere

3.1: trifluoroacetic acid / dichloromethane / 16 h / 20 °C / Inert atmosphere; Darkness

3.2: 2 h / 20 °C

4.1: zinc(II) acetate dihydrate / methanol; chloroform / 20 °C / Darkness

With n-butyllithium; palladium on activated charcoal; zinc(II) acetate dihydrate; trifluoroacetic acid; In tetrahydrofuran; methanol; hexane; dichloromethane; chloroform;
DOI:10.1021/cm2004648

Reference yield:

: 51760-23-7
1-bromo-3,5-bis(bromomethyl)benzene

: 1312229-53-0
[5,15-bis(3,5-di-n-tridecylphenyl)-porphyrinato(2-)-κN21,κN22,κN23,κN24] zinc(II)

Guidance literature:: Multi-step reaction with 6 steps

1.1: 16 h / Inert atmosphere; Reflux

2.1: sodium hydride / tetrahydrofuran / 16 h / Inert atmosphere; Reflux

3.1: palladium on activated charcoal / tetrahydrofuran / 20 h / 22 °C / Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -60 °C / Inert atmosphere

4.2: 2 h / 20 °C / Inert atmosphere

5.1: trifluoroacetic acid / dichloromethane / 16 h / 20 °C / Inert atmosphere; Darkness

5.2: 2 h / 20 °C

6.1: zinc(II) acetate dihydrate / methanol; chloroform / 20 °C / Darkness

With n-butyllithium; palladium on activated charcoal; zinc(II) acetate dihydrate; sodium hydride; trifluoroacetic acid; In tetrahydrofuran; methanol; hexane; dichloromethane; chloroform; 2.1: Horner-Wadsworth-Emmons olefination;
DOI:10.1021/cm2004648