1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Base Information

Chemical Name:1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol
CAS No.:106988-92-5
Molecular Formula:C₂₈H₃₀O₅
Molecular Weight:446.543
Hs Code.:

Synonyms:1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

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Chemical Property of 1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

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Technology Process of 1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

There total 7 articles about 1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 85716-46-7
1D-(1,3/2)-1,2,3-tri-O-benzyl-4-methylene-5-cyclohexen-1,2,3-triol

: 106988-92-5
1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

: 148347-74-4
(1R,4S,5R,6S)-4,5,6-tri(benzyloxy)-1-C-(hydroxymethyl)cyclohex-2-en-1-ol

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol; for 0.75h;

Reference yield:

: 100-39-0
benzyl bromide

: 106988-92-5
1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaH / 1) DMF, 50 min, 2) 0 deg C, 5 h

2: 21 percent / OsO₄, N-methylmorpholine N-oxide hydrate / acetone; H₂O; 2-methyl-propan-2-ol / 0.75 h

With osmium(VIII) oxide; sodium hydride; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol;

Reference yield:

: 97747-51-8
(1R)-(-)-1,2,3-tri-O-acetyl-(1,3/2,4,6)-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol

: 106988-92-5
1L-(1,2,4/3)-2,3,4-tri-O-benzyl-1-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 4 steps

1: DBU / toluene / 2.5 h / Heating

2: 1M methanolic NaOMe / 0.5 h / 0 °C

3: 1) NaH / 1) DMF, 50 min, 2) 0 deg C, 5 h

4: 21 percent / OsO₄, N-methylmorpholine N-oxide hydrate / acetone; H₂O; 2-methyl-propan-2-ol / 0.75 h

With osmium(VIII) oxide; sodium methylate; sodium hydride; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In water; acetone; toluene; tert-butyl alcohol;