(1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

Base Information

• Chemical Name: (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose
• CAS No.: 1418182-74-7
• Molecular Formula: C₂₆H₄₄O₅Si₂
• Molecular Weight: 492.803

Synonyms:(1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

Chemical Property of (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

There total 3 articles about (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane (69304-37-6) + C14H18O4 (1418182-76-9) → (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose (1418182-74-7)

Guidance literature:

With pyridine; at 20 ℃; for 3h;

DOI:10.1016/j.tet.2012.11.016

Reference yield:

C17H22O4 (1418182-75-8) → (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose (1418182-74-7)

Guidance literature:

Multi-step reaction with 2 steps

1: DOWEX(H⁺)50WX₈-100 / methanol / 26 h

2: pyridine / 3 h / 20 °C

With pyridine; In methanol;

DOI:10.1016/j.tet.2012.11.016

Reference yield:

α-(1R,5R,8R)-3,3-dimethyl-6-phenyl-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane (389633-39-0) → (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose (1418182-74-7)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h

2: DOWEX(H⁺)50WX₈-100 / methanol / 26 h

3: pyridine / 3 h / 20 °C

With pyridine; tetrabutyl ammonium fluoride; In tetrahydrofuran; methanol;

DOI:10.1016/j.tet.2012.11.016

upstream raw materials:

1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane

C₁₄H₁₈O₄

C₁₇H₂₂O₄

α-(1R,5R,8R)-3,3-dimethyl-6-phenyl-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

Downstream raw materials:

(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

(1′S,2′R,3′R,4′R)-1′-(2-formylethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

(1′S,2′R,3′R,4′R)-1′-[(N-3-methoxy-2-methylacryoyl)ureido]-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxy-ribose

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1418182-74-7 (1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

Send

Send

Metric Ton KG G Pound L ML

Send

Send