(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Base Information

Chemical Name:(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose
CAS No.:1418182-77-0
Molecular Formula:C₂₇H₄₆O₅Si₂
Molecular Weight:506.83
Hs Code.:

Synonyms:(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

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Chemical Property of (1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

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Technology Process of (1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

There total 4 articles about (1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 1418182-74-7
(1'S,2'R,3'R,4'R)-1'-allyl-1'-phenyl-3',5'-O-tetraisopropyl-disiloxyribose

: 74-88-4
methyl iodide

: 1418182-77-0
(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; for 2h;
DOI:10.1016/j.tet.2012.11.016

Reference yield:

: 1418182-75-8
C₁₇H₂₂O₄

: 1418182-77-0
(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: Multi-step reaction with 3 steps

1: DOWEX(H⁺)50WX₈-100 / methanol / 26 h

2: pyridine / 3 h / 20 °C

3: sodium hexamethyldisilazane / tetrahydrofuran / 2 h

With pyridine; sodium hexamethyldisilazane; In tetrahydrofuran; methanol;
DOI:10.1016/j.tet.2012.11.016

Reference yield:

: 1418182-76-9
C₁₄H₁₈O₄

: 1418182-77-0
(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 3 h / 20 °C

2: sodium hexamethyldisilazane / tetrahydrofuran / 2 h

With pyridine; sodium hexamethyldisilazane; In tetrahydrofuran;
DOI:10.1016/j.tet.2012.11.016