(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Base Information

Chemical Name:(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose
CAS No.:1418182-79-2
Molecular Formula:C₂₆H₄₇NO₅Si₂
Molecular Weight:509.834
Hs Code.:

Synonyms:(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Suppliers and Price of (1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

There total 7 articles about (1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1418182-80-5
C₂₆H₄₅NO₆Si₂

: 1418182-79-2
(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: With sodium tetrahydroborate; nickel dichloride; In methanol; at -78 ℃; for 2h;
DOI:10.1016/j.tet.2012.11.016

Reference yield:

: 1418182-78-1
(1′S,2′R,3′R,4′R)-1′-(2-formylethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

: 1418182-79-2
(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine; hydroxylamine hydrochloride / ethanol / 16 h / 70 °C

2: nickel dichloride; sodium tetrahydroborate / methanol / 2 h / -78 °C

With pyridine; sodium tetrahydroborate; hydroxylamine hydrochloride; nickel dichloride; In methanol; ethanol;
DOI:10.1016/j.tet.2012.11.016

Reference yield:

: 1418182-77-0
(1′S,2′R,3′R,4′R)-1′-allyl-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

: 1418182-79-2
(1′S,2′R,3′R,4′R)-1′-(2-aminoethyl)-2′-methoxy-1′-phenyl-3′,5′-O-tetraisopropyldisiloxyribose

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine; osmium(VIII) oxide; sodium periodate / water / 3 h

2: pyridine; hydroxylamine hydrochloride / ethanol / 16 h / 70 °C

3: nickel dichloride; sodium tetrahydroborate / methanol / 2 h / -78 °C

With pyridine; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; hydroxylamine hydrochloride; nickel dichloride; In methanol; ethanol; water;
DOI:10.1016/j.tet.2012.11.016