Technology Process of [PtCl(2,4-di(2'-pyridyl)-6-(p-tolyl)-1,3,5-triazine)](ClO4)
There total 1 articles about [PtCl(2,4-di(2'-pyridyl)-6-(p-tolyl)-1,3,5-triazine)](ClO4) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
water; acetonitrile;
a soln. of triazine-compound and Pt-compound in acetonitrile/H2O (1/1, v/v) was refluxed for 24 h, reduced in vol., a soln. in DMF was filtered into a satd. aq. Mg(ClO4)2, the mixt. was stirred overnight at room temp.; filtered, washed with water and ether, dried in a vac. oven; elem. anal.;
DOI:10.1021/om701285c
- Guidance literature:
-
With
potassium hydroxide; copper(l) iodide;
In
N,N-dimethyl-formamide;
C6H5C2H was added to a mixt. of KOH in DMF purged with Ar for 30 min, stirred for 30 min under Ar, complex and CuI were added, the mixt. was stirred under Ar at room temp. for 24 h; filtered, ether was added, ppt. was recrystd. twice from acetonitrile and ether; elem. anal.;
DOI:10.1021/om701285c
- Guidance literature:
-
With
potassium hydroxide; copper(l) iodide;
In
methanol;
pentyne was added to a mixt. of KOH in methanol purged with Ar for 30 min, stirred for 30 min under Ar, complex and CuI were added, the mixt. was stirred under Ar at room temp. for 48 h; the solvent was removed under reduced pressure, extd. with CH2Cl2, driedover anhyd. Na2SO4, passed through a short silica gel column twice, CH2 Cl2/acetone 20/1, v/v, recrystd. from CH2Cl2 and ether; elem. anal.;
DOI:10.1021/om701285c
