Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate

Base Information

Chemical Name:Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate
CAS No.:35909-01-4
Molecular Formula:C₆H₁₀N₂O₃
Molecular Weight:158.157
Hs Code.:
UNII:XG4AEK1AEE
DSSTox Substance ID:DTXSID40957327
Mol file:35909-01-4.mol

Synonyms:35909-01-4;XG4AEK1AEE;Methyl N-nitroso-L-prolinate;Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate;UNII-XG4AEK1AEE;Methyl 1-nitrosoprolinate;SCHEMBL17393339;DTXSID40957327;TWHZGAYWZCCUSQ-YFKPBYRVSA-N;2-Pyrrolidinecarboxylic acid, 1-nitroso-, methyl ester, (S)-;1-NITROSO-L-PROLINE METHYL ESTER;L-PROLINE, 1-NITROSO-, METHYL ESTER;(S)-1-nitroso-pyrrolidine-2-carboxylic acid methyl ester

Suppliers and Price of Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate

Chemical Property:

Vapor Pressure:0.004mmHg at 25°C
Boiling Point:279.5°Cat760mmHg
Flash Point:122.8°C
PSA：58.97000
Density:1.36g/cm³
LogP:0.24310
XLogP3:0.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:2
Exact Mass:158.06914219
Heavy Atom Count:11
Complexity:171

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1CCCN1N=O
Isomeric SMILES:COC(=O)[C@@H]1CCCN1N=O

Technology Process of Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate

There total 7 articles about Methyl (S)-1-nitroso-2-pyrrolidinecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 67-56-1
methanol

: 7519-36-0
nitrosoproline

: 71922-04-8,35909-01-4
(S)-1-nitrosopyrrolidine-2-carboxylic acid methyl ester

Guidance literature:: With sulfuric acid; at 20 ℃; for 12h;
DOI:10.1021/jo800719j

Reference yield: 54.0%

: 2577-48-2
methyl (2S)-pyrrolidine carboxylate

: 71922-04-8,35909-01-4
(S)-1-nitrosopyrrolidine-2-carboxylic acid methyl ester

Guidance literature:: With 2-nitropropane; 4-(4-fluorophenyl)naphthalene-1,2-dione; oxygen; at 80 ℃; for 12h;
DOI:10.1021/acscatal.9b03442

Reference yield:

: 2133-40-6
L-proline methyl ester monohydrochloride

: 71922-04-8,35909-01-4
(S)-1-nitrosopyrrolidine-2-carboxylic acid methyl ester

Guidance literature:: L-proline methyl ester monohydrochloride; With toluene-4-sulfonic acid; In dichloromethane; for 0.166667h; Inert atmosphere;

With sodium nitrite; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;