(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Base Information

Chemical Name:(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol
CAS No.:1448529-90-5
Molecular Formula:C₅₂H₇₁N₃O₈
Molecular Weight:866.151
Hs Code.:

Synonyms:(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Suppliers and Price of (2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

There total 10 articles about (2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: C₅₆H₇₅N₃O₁₀

: 1448529-90-5
(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Guidance literature:: With sodium methylate; In tetrahydrofuran; methanol;

Reference yield: 80.0%

: 1256376-22-3
(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-3,4-di-tert-butyldimethylsilyloxyoctadecane

: 1448529-90-5
(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2013.06.051

Reference yield:

: 201002-41-7
(2R,3S,4R)-2-azidooctadecane-1,3,4-triol

: 1448529-90-5
(2S,3S,4R)-1-O-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)-2-azido-1,3,4-octadecanetriol

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-dimethylpyridine / dichloromethane / 2.5 h / 0 - 20 °C / Inert atmosphere

2: trifluoroacetic acid / water; tetrahydrofuran / 0 °C / Inert atmosphere

3: N-iodo-succinimide; trifluorormethanesulfonic acid / dichloromethane; diethyl ether / 2 h / 20 °C / Inert atmosphere; Molecular sieve

4: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; N-iodo-succinimide; trifluorormethanesulfonic acid; tetrabutyl ammonium fluoride; trifluoroacetic acid; In tetrahydrofuran; diethyl ether; dichloromethane; water;
DOI:10.1016/j.tet.2013.06.051