ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾

Base Information

• Chemical Name: ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾
• CAS No.: 102286-39-5
• Molecular Formula: C₂₈H₅₂P₂Pt
• Molecular Weight: 645.748
• Mol file: 102286-39-5.mol

Synonyms:ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾

Chemical Property of ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾

There total 4 articles about ethylene{bis(dicyclohexylphosphino)ethane}platinum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II) + methane (34557-54-5,27936-85-2) → cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-49-8) + ethylene{bis(dicyclohexylphosphino)ethane}platinum(0) (102286-39-5) + cis-methylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-50-1) + 2,2-dimethylpropane (463-82-1)

Guidance literature:

In cyclohexane; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in cyclohexane under methane via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 45°C for 39h at 2050 psi; Kinetics;

DOI:10.1021/ja00213a016

Reference yield:

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II) + ethene (74-85-1) → ethylene{bis(dicyclohexylphosphino)ethane}platinum(0) (102286-39-5)

Guidance literature:

In Cyclohexane-d12; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in cyclohexane-d12 under 1 atm ethylene via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 69°C for 1 h; Kinetics;

DOI:10.1021/ja00213a016

Reference yield:

dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) (90667-70-2) + ethene (74-85-1) → ethylene{bis(dicyclohexylphosphino)ethane}platinum(0) (102286-39-5)

Guidance literature:

With Na#Hg; In tetrahydrofuran; reducing a THF soln. of Pt complex with Na amalgam under C2H4;

DOI:10.1039/b107015k

upstream raw materials:

dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

ethene

bis(cycloocta-1,5-diene)platinum⁽⁰⁾

1,2-bis-(dicyclohexylphosphino)ethane

Downstream raw materials:

[Pt(η2-(prop-1-ynyl)diphenylphosphine)(1,2-bis(dicyclohexylphosphino)ethane)]

[Pt(η2-Ph2P(S)C2Me)(1,2-bis(dicyclohexylphosphino)ethane)]

[Pt(η2-Ph2P(O)C2Me)(1,2-bis(dicyclohexylphosphino)ethane)]

[PtCl(C(=CHMe)PPh₂)(1,2-bis(dicyclohexylphosphino)ethane)]