tetracarbonyl(triphenylphosphine)manganate

Base Information

• Chemical Name: tetracarbonyl(triphenylphosphine)manganate
• CAS No.: 53418-18-1
• Molecular Formula: C₂₂H₁₅MnO₄P
• Molecular Weight: 429.27
• Mol file: 53418-18-1.mol

Synonyms:tetracarbonyl(triphenylphosphine)manganate

Chemical Property of tetracarbonyl(triphenylphosphine)manganate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of tetracarbonyl(triphenylphosphine)manganate

There total 2 articles about tetracarbonyl(triphenylphosphine)manganate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

(CO)4Mn(P(C6H5)3)2(1+)*PF6(1-)=(CO)4Mn(P(C6H5)3)2PF6 (70083-76-0) → tetracarbonyl(triphenylphosphine)manganate (53418-18-1) + HMn(CO)3{P(C6H5)3}2 (160024-77-1,17030-38-5,16972-17-1)

Guidance literature:

With tetrabutylammonium perchlorate; In tetrahydrofuran; Electrochem. Process; 0.05 M soln. of metal carbonyl in THF containing 0.1 M Bu4NClO4 was reduced at Pt electrode under dry inert atm. in semidarkness until slightlymore than 1 electron/mol was passed; not isolated, identified by IR; the minor component HMn(CO)4(PPh3)2 wasidentified by NMR;

DOI:10.1021/om00136a015

Reference yield:

pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1) + disodium tetracarbonylferrate → iron pentacarbonyl (13463-40-6,37220-42-1) + tetracarbonyl(triphenylphosphine)manganate (53418-18-1)

Guidance literature:

In acetonitrile; byproducts: CO; 27°C; IR;

DOI:10.1021/om00054a047

Reference yield: 86.0%

pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1) + tetracarbonyl(triphenylphosphine)manganate (53418-18-1) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4)

Guidance literature:

With tetrabutylammonium perchlorate; In tetrahydrofuran; 5-mL aliquot of 1E-2 M Mn(CO)4PPh3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5PPh3(1+) in THF contg. 0.3 M TBAP at 22°C, react. complete within 5 min; not isolated; detected by IR;

DOI:10.1021/om00152a010

upstream raw materials:

(CO)4Mn(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(CO)4Mn(P(C₆H₅)3)2PF₆

pentacarbonyl(triphenylphosphine)manganese(I) cation

Downstream raw materials:

pentacarbonylmanganate

dimanganese decacarbonyl

Mn₂(CO)9(triphenylphosphine)

dimanganese octacarbonyl di-(triphenyl phosphine)