Phosphorodiamidic chloride, N,N'-diphenyl-

Base Information

• Chemical Name: Phosphorodiamidic chloride, N,N'-diphenyl-
• CAS No.: 5625-99-0
• Molecular Formula: C12H12 Cl N2 O P
• Molecular Weight: 266.667
• European Community (EC) Number: 227-063-9
• NSC Number: 57566
• UNII: ZC3J6NU3CZ
• DSSTox Substance ID: DTXSID40204803
• Nikkaji Number: J50.414I
• Wikidata: Q83078264
• Mol file: 5625-99-0.mol

Synonyms:5625-99-0;Phosphorodiamidic chloride, N,N'-diphenyl-;Dianilidophosphochloridate;Phosphine oxide, deanilenochloro-;Phosphoric acid dianilide chloride;N-[anilino(chloro)phosphoryl]aniline;N,N'-Diphenyldiamidophosphoric chloride;N,N'-Diphenylphosphorodiamidic chloride;Phosphine oxide, chlorobis(phenylamino)-;Phosphine oxide, dianilinochloro-;EINECS 227-063-9;NSC 57566;BRN 2215936;Diamidophosphoryl chloride, N,N'-diphenyl-;NSC-57566;4-12-00-01087 (Beilstein Handbook Reference);WLN: RMPO&GMR;ZC3J6NU3CZ;C12H12ClN2OP;NCIOpen2_002535;SCHEMBL9439409;DTXSID40204803;Bis(phenylamino)phosphinyl chloride;C12-H12-Cl-N2-O-P;NSC57566;Diamidophosphoryl chloride,N'-diphenyl-;Phosphorodiamidic chloride,N'-diphenyl-;LS-107996

Chemical Property of Phosphorodiamidic chloride, N,N'-diphenyl-

Chemical Property:

• Melting Point: 167 °C
• Boiling Point: 382.5°Cat760mmHg
• PKA: -1.07±0.38(Predicted)
• Flash Point: 185.1°C
• PSA: 50.94000
• Density: 1.39g/cm³
• LogP: 4.70350
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 266.0375777
• Heavy Atom Count: 17
• Complexity: 252

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)NP(=O)(NC2=CC=CC=C2)Cl

Technology Process of Phosphorodiamidic chloride, N,N'-diphenyl-

There total 6 articles about Phosphorodiamidic chloride, N,N'-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

aniline (62-53-3) → N,N'-diphenylphosphorodiamidic chloride (5625-99-0)

Guidance literature:

With trichlorophosphate; In tetrahydrofuran; at 4 ℃; Inert atmosphere; Schlenk technique; Cooling with ice;

DOI:10.3762/bjoc.10.18

Reference yield:

aniline hydrochloride (142-04-1,36663-09-9) → N,N'-diphenylphosphorodiamidic chloride (5625-99-0)

Guidance literature:

With trichlorophosphate;

Reference yield:

→ N,N'-diphenylphosphorodiamidic chloride (5625-99-0)

Guidance literature:

With phosphorus pentachloride;

upstream raw materials:

aniline hydrochloride

aniline

tetrachloromethane

trichlorophosphate

Downstream raw materials:

diphosphoric acid tetraanilide

methyl NN'diphenylphosphorodiamidate

N,N'-diphenyl-diamidophosphoric acid-(2-dimethylamino-ethyl ester)

bis(phenylamino)phenylphosphine oxide