methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside

Base Information

• Chemical Name: methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside
• CAS No.: 218445-42-2
• Molecular Formula: C₂₉H₃₄O₅
• Molecular Weight: 462.586
• Mol file: 218445-42-2.mol

Synonyms:methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside

Chemical Property of methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside

There total 2 articles about methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

methyl 3,4,6-tri-Obenzyl-2-deoxy-2-C-methylene-α-D-lyxo-hexopyranoside (153081-98-2) → methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside (218445-42-2)

Guidance literature:

With hydrogen;

DOI:10.1016/j.tetasy.2005.04.009

Reference yield: 67.0%

methanol (67-56-1) + (1S,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-benzyloxymethyl-2-oxa-bicyclo[4.1.0]heptane (162428-29-7) → methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside (218445-42-2)

Guidance literature:

With Zeise's dimer; In dichloromethane; for 15h; Ambient temperature;

DOI:10.1021/ja982964k

Reference yield: 48.0%

methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranoside (218445-42-2) → 3,4,6-tri-O-benzyl-2-deoxy-2-C-methyl-α-D-talohexopyranosyl hydroperoxide

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In 1,4-dioxane; at 20 ℃;

DOI:10.1016/j.tetasy.2005.04.009

upstream raw materials:

methanol

(1S,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-benzyloxymethyl-2-oxa-bicyclo[4.1.0]heptane

methyl 3,4,6-tri-Obenzyl-2-deoxy-2-C-methylene-α-D-lyxo-hexopyranoside