sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

Base Information

Chemical Name:sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate
CAS No.:345994-94-7
Molecular Formula:C₃₆H₅₂BSi₄*H₁₂NaO₆
Molecular Weight:739.043
Hs Code.:

Synonyms:sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

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Chemical Property of sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

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Technology Process of sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

There total 1 articles about sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 109-63-7
boron trifluoride diethyl etherate

: 6999-03-7
1-bromo-4-(trimethylsilyl)benzene

: 7647-14-5
sodium chloride

: 345994-94-7
sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

Guidance literature:: With t-BuLi; In diethyl ether; water; pentane; under N2 atm. to soln. p-bromo(trimethylsilyl)benzene in Et2O was t-BuLiin pentane at -78°C, stirred for 3 h, allowed to warm to 0.degre e.C, cooled to -78°C, BF3*OEt2 was added, allowed to reach room temp. for 16 h, aq. NaCl was added; Et2O layer was separated, washed with water, and dried over MgSO4, solvent was removed, residue was washed with pentane;
DOI:10.1021/om0009177

Reference yield: 76.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 345994-94-7
sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 345994-97-0
rhodium(I) [bis(1,2-bis(diphenylphosphino)ethane)] tetrakis[p-(trimethylsilyl)phenyl]borate

Guidance literature:: In dichloromethane; isopropyl alcohol; under N2 atm. dppe in CH2Cl2 was added to soln. (Rh(1,5-COD)Cl)2 in CH2Cl2 and stirred for 1 h, suspn. (Na(H2O)6)(B(C6H4SiMe3)4) in isopropanol was added and stirred for 4 h; soln. was filtered, volatiles were removed in vacuo, solid was taken up in acetone, soln. was filtered, hexane was added; elem. anal.;
DOI:10.1021/om0009177

Reference yield: 65.0%

: 345994-94-7
sodium tetrakis[p-(trimethylsilyl)phenyl]borate hexahydrate

: 429-41-4
tetrabutyl ammonium fluoride

: 345994-96-9
tetrabutylammonium tetrakis[p-(trimethylsilyl)phenyl]borate

Guidance literature:: In tetrahydrofuran; under N2 atm. n-Bu4NBr in THF was added to soln. (Na(H2O)6)(B(C6H4SiMe3)4) in THF and stirred for 1.5 h; H2O was added, mixt. was stirred for 30 min, ppt. was collected, washed with H2O, and dried in vacuo; elem. anal.;
DOI:10.1021/om0009177