1-naphthyldiphenylbismuthane

Base Information

• Chemical Name: 1-naphthyldiphenylbismuthane
• CAS No.: 66172-96-1
• Molecular Formula: C₂₂H₁₇Bi
• Molecular Weight: 490.357
• Mol file: 66172-96-1.mol

Synonyms:1-naphthyldiphenylbismuthane

Chemical Property of 1-naphthyldiphenylbismuthane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-naphthyldiphenylbismuthane

There total 29 articles about 1-naphthyldiphenylbismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.2%

1-naphthyldiphenylbismuth dichloride → 1-naphthyldiphenylbismuthane (66172-96-1)

Guidance literature:

In ethanol; warming;

DOI:10.1021/ja01860a068

Reference yield: 57.0%

diphenylbismuth(III) chloride (5153-28-6) + 1-naphthylmagnesiumbromide (703-55-9) → 1-naphthyldiphenylbismuthane (66172-96-1)

Guidance literature:

In diethyl ether; 0°C; pouring into H2O, evapn. of ether, taking of the residue up with CH3OH;

Reference yield: 40.8%

1-Iodonaphthalene (90-14-2) + diphenylbismuthanyl bromide (39248-62-9) → 1-naphthyldiphenylbismuthane (66172-96-1)

Guidance literature:

With sodium; In diethyl ether; ammonia; byproducts: naphtaline, NaBr; react. of Na and (C6H5)2BiBr in liq. NH3, react. of (C6H5)2BiN intermediate (without isolation) with 1-IC10H7 in (C2H5)2O;

upstream raw materials:

tri(naphthalen-1-yl)bismuth

triphenylbismuthane

diethyl ether

(1-C₁₀H₇)BiBr₂

Downstream raw materials:

1-Iodonaphthalene

diphenylbismuth(III) chloride

naphthalene

benzene