iododiphenylbismuth(III)

Base Information

• Chemical Name: iododiphenylbismuth(III)
• CAS No.: 95825-92-6
• Molecular Formula: C₁₂H₁₀BiI
• Molecular Weight: 490.096
• Mol file: 95825-92-6.mol

Synonyms:iododiphenylbismuth(III)

Chemical Property of iododiphenylbismuth(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iododiphenylbismuth(III)

There total 16 articles about iododiphenylbismuth(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

diphenylbismuth(III) chloride (5153-28-6) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → iododiphenylbismuth(III) (95825-92-6)

Guidance literature:

In acetone; byproducts: NaCl; Equimolar amounts were allowed to react in acetone at room temp.; F.F.Blicke, U.O.Oakdale, and F.D.Smith, J. Am. Chem. Soc., 1931, 53,1025;; filtered, the soln. was treated with H2O, ppt. was filtered off, washedwith water, dried over P4O10;;

Reference yield: 91.0%

sodium 8-quinolinolate (2872-54-0) + diiodo(phenyl)bismuth(III) (39110-03-7) → iodobis(quinolin-8-olato)bismuth(III) (219745-49-0) + triphenylbismuthane (603-33-8) + iododiphenylbismuth(III) (95825-92-6)

Guidance literature:

In ethanol; byproducts: NaI; N2-atmosphere; addn. of Na-salt to soln. of PhBiI2 (molar ratio 1 : 1; pptn.); stirring (3 h), filtration, washing (EtOH, light petroleum), drying; elem. anal.;

DOI:10.1071/ch9960231

Reference yield: 70.0%

phenyllithium (591-51-5) + 2,2'-Biphenyldiyliodbismutan → iododiphenylbismuth(III) (95825-92-6)

Guidance literature:

In diethyl ether;

DOI:10.1016/S0022-328X(00)88225-X

upstream raw materials:

triphenylbismuthane

tetraphenyldibismuthine

iodine

diphenylbismuth(III) chloride

Downstream raw materials:

triphenylbismuthane

tetraphenyldibismuthine

sodium diphenylbismuthide

1-naphthyldiphenylbismuthane

Refernces

• 1、 Smith, Katharine A.,Deacon, Glen B.,Jackson, W. Roy,Miller, Jack M.. "Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives". . p. 231 - 238. Retrieved 2007/10/03.
• 2、 Calderazzo, Fausto,Poli, Rinaldo,Pelizzi, Giancarlo. "Synthesis, Reactivity, and Crystal and Molecular Structure of Tetraphenyldibismuth, Bi2Ph4". . p. 2365 - 2370. Retrieved 2007/10/02.