((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

Base Information

Chemical Name:((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3
CAS No.:155019-75-3
Molecular Formula:C₂₇H₂₁F₁₅MoN₆Si
Molecular Weight:838.505
Hs Code.:

((C<sub>6</sub>F<sub>5</sub>NCH<sub>2</sub>CH<sub>2</sub>)3N)MoNNSi(CH<sub>3</sub>)3

Synonyms:((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

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Chemical Property of ((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

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Technology Process of ((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

There total 2 articles about ((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 75-77-4
chloro-trimethyl-silane

: 155019-65-1
((C₆F₅NCH₂CH₂)3N)MoOTf

: 7727-37-9
nitrogen

: 155019-75-3
((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

Guidance literature:: With sodium amalgam; In tetrahydrofuran; diethyl ether; under N2 atm. sodium amalgam was covered with THF, (C6F5N3N)MoOTf was added and react. mixt. was stirred at room temp. for 3 h, soln. was decanted and evapd., residue was dissolved in Et2O, cooled to -40°C, soln. Me3SiCl in THF was added; soln. allowed to warm to room temp. for 30 min, pentane was added, filtered, concd., pentane was added and cooled to -40°C;
DOI:10.1021/ic001123n

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 155019-73-1
Mo(N(CH₂CH₂NC₆F₅)3)NNSi(CH(CH₃)2)3

: 155019-75-3
Mo(N(CH₂CH₂NC₆F₅)3)NNSi(CH₃)3

Guidance literature:: With CsF; In tetrahydrofuran; under exclusion of air; excess of CsF was added to a soln. of the Mo complex in THF, stirred at room temp. for 24 h, Me3SiCl was added; not isolated;
DOI:10.1021/ja00089a028

Reference yield: 96.0%

: 155019-75-3
((C₆F₅NCH₂CH₂)3N)MoNNSi(CH₃)3

: 333-27-7
methyl trifluoromethanesulfonate

: 351025-87-1
(((C₆F₅NCH₂CH₂)3N)Mo=N-NMe₂)OTf

Guidance literature:: In toluene; under N2 atm. methyl triflate was added to soln. ((C6F5NCH2CH2)3N)MoNNSiMe3 in toluene and heated to 45°C overnight; ppt. was collected, washed with Et2O, and dried in vacuo; elem. anal.;
DOI:10.1021/ic001123n