(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

Base Information

Chemical Name:(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester
CAS No.:77523-35-4
Molecular Formula:C₁₉H₂₄O₈
Molecular Weight:380.395
Hs Code.:

Synonyms:(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

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Chemical Property of (3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

Chemical Property:

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Technology Process of (3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

There total 7 articles about (3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 77523-34-3
(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

: 77523-35-4
(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

Guidance literature:: With hydrogen; platinum(IV) oxide; In ethyl acetate; under 760 Torr;
DOI:10.1021/ja00397a059

Reference yield:

: 14260-67-4
(3aR,5R,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

: 77523-35-4
(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 69 percent / KO-t-Bu / tetrahydrofuran

2: 1.) PTSA, 2.) Ag₂CO₃/celite / 1.) CH₃CN, H₂O, 2.) benzene

3: 95 percent / pyridine / CH₂Cl₂

4: 95 percent / 5percentPd(PPh₃)4 / tetrahydrofuran

5: 91 percent / hydrogen / PtO₂ / ethyl acetate / 760 Torr

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Celite; potassium tert-butylate; hydrogen; toluene-4-sulfonic acid; silver carbonate; platinum(IV) oxide; In tetrahydrofuran; dichloromethane; ethyl acetate;
DOI:10.1021/ja00397a059

Reference yield:

: 50-99-7
D-glucose

: 77523-35-4
(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-octanedioic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: ZnCl₂, H₃PO₄ / 72 h / Ambient temperature

2: 82 percent / pyridine

4: 69 percent / KO-t-Bu / tetrahydrofuran

5: 1.) PTSA, 2.) Ag₂CO₃/celite / 1.) CH₃CN, H₂O, 2.) benzene

6: 95 percent / pyridine / CH₂Cl₂

7: 95 percent / 5percentPd(PPh₃)4 / tetrahydrofuran

8: 91 percent / hydrogen / PtO₂ / ethyl acetate / 760 Torr

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; phosphoric acid; Celite; potassium tert-butylate; hydrogen; toluene-4-sulfonic acid; silver carbonate; zinc(II) chloride; platinum(IV) oxide; In tetrahydrofuran; pyridine; dichloromethane; ethyl acetate;
DOI:10.1021/ja00397a059