(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Base Information

Chemical Name:(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester
CAS No.:77523-34-3
Molecular Formula:C₁₉H₂₂O₈
Molecular Weight:378.379
Hs Code.:

Synonyms:(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Suppliers and Price of (E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

There total 7 articles about (E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 77523-33-2
Benzoic acid (3R,5R)-2-oxo-5-((Z)-propenyl)-tetrahydro-furan-3-yl ester

: 77523-34-3
(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran;
DOI:10.1021/ja00397a059

Reference yield:

: 14260-67-4
(3aR,5R,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

: 77523-34-3
(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 69 percent / KO-t-Bu / tetrahydrofuran

2: 1.) PTSA, 2.) Ag₂CO₃/celite / 1.) CH₃CN, H₂O, 2.) benzene

3: 95 percent / pyridine / CH₂Cl₂

4: 95 percent / 5percentPd(PPh₃)4 / tetrahydrofuran

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Celite; potassium tert-butylate; toluene-4-sulfonic acid; silver carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00397a059

Reference yield:

: 50-99-7
D-glucose

: 77523-34-3
(E)-(3R,7R)-7-Benzoyloxy-2-methoxycarbonyl-3-methyl-oct-4-enedioic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: ZnCl₂, H₃PO₄ / 72 h / Ambient temperature

2: 82 percent / pyridine

4: 69 percent / KO-t-Bu / tetrahydrofuran

5: 1.) PTSA, 2.) Ag₂CO₃/celite / 1.) CH₃CN, H₂O, 2.) benzene

6: 95 percent / pyridine / CH₂Cl₂

7: 95 percent / 5percentPd(PPh₃)4 / tetrahydrofuran

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; phosphoric acid; Celite; potassium tert-butylate; toluene-4-sulfonic acid; silver carbonate; zinc(II) chloride; In tetrahydrofuran; pyridine; dichloromethane;
DOI:10.1021/ja00397a059