4-(Allylseleno)-1-chlorobenzene

Base Information

Chemical Name:4-(Allylseleno)-1-chlorobenzene
CAS No.:17508-29-1
Molecular Formula:C9H9 Cl Se
Molecular Weight:231.583
Hs Code.:2931900090
European Community (EC) Number:241-513-1
DSSTox Substance ID:DTXSID80169927
Nikkaji Number:J287.067C
Wikidata:Q83039734
Mol file:17508-29-1.mol

Synonyms:4-(Allylseleno)-1-chlorobenzene;17508-29-1;1-chloro-4-prop-2-enylselanylbenzene;EINECS 241-513-1;C9H9ClSe;C9-H9-Cl-Se;Allyl 4-chlorophenyl selenide;DTXSID80169927

Suppliers and Price of 4-(Allylseleno)-1-chlorobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 4-(Allylseleno)-1-chlorobenzene

Chemical Property:

Vapor Pressure:0.0216mmHg at 25°C
Boiling Point:258.9°Cat760mmHg
Flash Point:110.4°C
PSA：0.00000
Density:g/cm³
LogP:2.27380
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:231.95580
Heavy Atom Count:11
Complexity:117

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CC[Se]C1=CC=C(C=C1)Cl

Technology Process of 4-(Allylseleno)-1-chlorobenzene

There total 5 articles about 4-(Allylseleno)-1-chlorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 20541-49-5
bis(p-chlorophenyl) diselenide

: 106-95-6
allyl bromide

: 17508-29-1
allyl(4-chlorophenyl)selane

Guidance literature:: With samarium; cadmium(II) chloride; In water; N,N-dimethyl-formamide; at 20 - 50 ℃; for 3.5h;
DOI:10.1080/00397910008087216

Reference yield:

: 637-87-6
1-Chloro-4-iodobenzene

: 17508-29-1
allyl(4-chlorophenyl)selane

Guidance literature:: Multi-step reaction with 2 steps

1: selenium; copper(II) oxide; potassium hydroxide / dimethyl sulfoxide / 90 °C / Inert atmosphere

2: sodium tetrahydroborate; ethanol / tetrahydrofuran / 0.42 h / 0 °C / Inert atmosphere

With selenium; sodium tetrahydroborate; ethanol; copper(II) oxide; potassium hydroxide; In tetrahydrofuran; dimethyl sulfoxide;
DOI:10.1021/acs.orglett.9b01092

Reference yield:

: 18925-10-5
allylzinc bromide

: 17508-29-1
allyl(4-chlorophenyl)selane

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; selenium; Yield given. Multistep reaction; 1.) THF, room temperature (1 h), reflux, 2.) THF, 40 deg, 12 h;
DOI:10.1080/00032719808006476