S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Base Information

Chemical Name:S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate
CAS No.:101540-18-5
Molecular Formula:C₂₃H₂₉NO₁₀S
Molecular Weight:511.55
Hs Code.:

Synonyms:S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Suppliers and Price of S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

There total 6 articles about S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 19879-84-6
tetraacetyl thioglucose

: 92988-96-0
N-hydroxy(2-phenylethyl)-oximidoyl chloride

: 101540-18-5
S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Guidance literature:: With triethylamine; In tetrahydrofuran; Reagent/catalyst; Solvent;
DOI:10.1055/s-0036-1591895

Reference yield:

: 1197-50-8
3-phenylpropanal oxime

: 101540-18-5
S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hypochlorite / dichloromethane; water

2: triethylamine / dichloromethane / 3 h / 20 °C

With sodium hypochlorite; triethylamine; In dichloromethane; water;
DOI:10.1016/j.tetlet.2011.01.117

Reference yield:

: 2280-44-6
D-Glucose

: 101540-18-5
S-(2',3',4',6'-tetra-O-acetyl-1-β-D-glucopyranosyl)-3-phenylpropanethiohydroximate

Guidance literature:: Multi-step reaction with 4 steps

1.1: perchloric acid / 3 h / 40 - 50 °C

1.2: 1.5 h / 20 °C

2.1: acetone / 0.5 h / Reflux

3.1: sodium sulfite; water / ethyl acetate / 1 h / 40 °C / Inert atmosphere

4.1: triethylamine / tetrahydrofuran

With perchloric acid; water; triethylamine; sodium sulfite; In tetrahydrofuran; ethyl acetate; acetone;
DOI:10.1055/s-0036-1591895