beta,2-Dinitro-3,4,5-trimethoxystyrene

Base Information

Chemical Name:beta,2-Dinitro-3,4,5-trimethoxystyrene
CAS No.:132256-98-5
Molecular Formula:C₁₁H₁₂N₂O₇
Molecular Weight:284.225
Hs Code.:
DSSTox Substance ID:DTXSID201188811
Nikkaji Number:J2.964.229J

Synonyms:132256-98-5;DTXSID201188811;beta,2-Dinitro-3,4,5-trimethoxystyrene;Benzene, 1,2,3-trimethoxy-4-nitro-5-(2-nitroethenyl)-, (E)-

Suppliers and Price of beta,2-Dinitro-3,4,5-trimethoxystyrene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of beta,2-Dinitro-3,4,5-trimethoxystyrene

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:284.06445073
Heavy Atom Count:20
Complexity:376

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=C(C(=C(C(=C1)C=C[N+](=O)[O-])[N+](=O)[O-])OC)OC
Isomeric SMILES:COC1=C(C(=C(C(=C1)/C=C/[N+](=O)[O-])[N+](=O)[O-])OC)OC

Technology Process of beta,2-Dinitro-3,4,5-trimethoxystyrene

There total 6 articles about beta,2-Dinitro-3,4,5-trimethoxystyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 75-52-5
nitromethane

: 55149-78-5
2-nitro-3,4,5-trimethoxybenzaldehyde

: 132256-98-5
1,2,3-trimethoxy-4-nitro-5-(2-nitrovinyl)benzene

Guidance literature:: With ammonium acetate; In acetic acid; at 100 ℃; for 1.5h;
DOI:10.1039/c0ob01038c

Reference yield: 37.0%

: 40663-31-8
1-(3,4,5-trimethoxyphenyl)-2-nitroethene

: 132256-98-5
1,2,3-trimethoxy-4-nitro-5-(2-nitrovinyl)benzene

Guidance literature:: With nitric acid; acetic anhydride; copper(II) nitrate; for 2h; Ambient temperature;

Reference yield:

: 66907-52-6
3,4,5-trimethoxy-2-nitrobenzoic acid

: 132256-98-5
1,2,3-trimethoxy-4-nitro-5-(2-nitrovinyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride-tetrahydrofuran complex / tetrahydrofuran / Reflux

2: dipyridinium dichromate / dichloromethane / 20 h / Molecular sieve

3: ammonium acetate / acetic acid / 1.5 h / 100 °C

With dipyridinium dichromate; boron trifluoride-tetrahydrofuran complex; ammonium acetate; In tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1039/c0ob01038c