(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

Base Information

Chemical Name:(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone
CAS No.:1092969-77-1
Molecular Formula:C₅₃H₈₉NO₆
Molecular Weight:836.293
Hs Code.:

Synonyms:(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

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Chemical Property of (S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

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Technology Process of (S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

There total 5 articles about (S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 114744-83-1,688763-83-9
(S)-benzyl (1-(N,O-dimethylhydroxylamine)-1-oxopropan-2-yl)carbamate

: 654065-52-8
1-bromo-3,4,5-tris-n-dodecyloxybenzene

: 1092969-77-1
(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

Guidance literature:: 1-bromo-3,4,5-tris-n-dodecyloxybenzene; With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 2h;

(S)-benzyl (1-(N,O-dimethylhydroxylamine)-1-oxopropan-2-yl)carbamate; In tetrahydrofuran; diethyl ether; hexane; at -78 - -20 ℃; for 4h;
DOI:10.1002/anie.200803242

Reference yield: 53.0%

: 3,4,5-tridodecyloxyphenyllithium

: 114744-83-1,688763-83-9
(S)-benzyl (1-(N,O-dimethylhydroxylamine)-1-oxopropan-2-yl)carbamate

: 1092969-77-1
(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

Guidance literature:: (S)-benzyl (1-(N,O-dimethylhydroxylamine)-1-oxopropan-2-yl)carbamate; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 2h;

3,4,5-tridodecyloxyphenyllithium; In tetrahydrofuran; hexane; at -20 ℃; for 3h;
DOI:10.1021/ja105221u

Reference yield:

: 2675-79-8
1-bromo-3,4,5-trimethoxybenzene

: 1092969-77-1
(S)-1-(benzyloxycarbonylamino)ethyl 3,4,5-tris(dodecanoxy)phenyl ketone

Guidance literature:: Multi-step reaction with 3 steps

1.1: boron tribromide / dichloromethane / 8 h / -78 - 20 °C

2.1: potassium carbonate / N,N-dimethyl-formamide / 20 h / 60 °C

3.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 - 20 °C

3.2: 3 h / -20 °C

With n-butyllithium; boron tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/chir.23395