dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾

Base Information

• Chemical Name: dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾
• CAS No.: 15377-00-1
• Molecular Formula: C₃₈H₃₀O₂P₂Pt
• Molecular Weight: 775.683
• Mol file: 15377-00-1.mol

Synonyms:dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾

Chemical Property of dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾

There total 16 articles about dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

platinum(II) chloride (10025-65-7) + zinc (7440-66-6) → dicarbonylbis(triphenylphosphine)platinum(0) (15377-00-1)

Guidance literature:

With carbon monoxide; triphenylphosphine; In tetrahydrofuran; byproducts: ZnCl2; refluxing 2 equiv. of PPh3 with PtCl2 (1 h), addn. of Zn-dust, stirring under CO for 6 h at room temp. (dissoln. of PtCl2(PPh3)2 intermediate); filtration, crystn. on addn. of EtOH and cooling to -10°C (under CO), washing (EtOH), drying (vac.); elem. anal.;

DOI:10.1016/S0020-1693(00)95469-0

Reference yield: 60.0%

trans-{PtH(C3H4O2)(PPh3)2}BF4 (95614-97-4) + bis(triphenylphosphine)iminium chloride (21050-13-5) → trans-chlorohydridobis(triphenylphosphine)platinum(II) (16841-99-9,25879-12-3,16902-93-5) + dicarbonylbis(triphenylphosphine)platinum(0) (15377-00-1) + 3Pt*3CO*4P(C6H5)3=Pt3(CO)3(P(C6H5)3)4 + {{(C6H5)3P}2Pt(H)(C(O)OCH2CH2Cl)}

Guidance literature:

In tetrahydrofuran; byproducts: ClCH2CH2OH; react. of starting materials (N2) is followed by IR (room temp.) and NMR spectroscopy (room temp., low temp.); concn. of soln. after 10 h, addn. of Et2O, filtration of pptd. solid (trans-((PPh3)2Pt(H)Cl)), washing (Et2O); identification by 1H-NMR;

DOI:10.1016/0022-328X(92)83290-X

Reference yield:

trans-(2,5-dichlorophenyl)hydridobis(triphenylphosphine)platinum → para-dichlorobenzene (106-46-7,84348-21-0) + dicarbonylbis(triphenylphosphine)platinum(0) (15377-00-1)

Guidance literature:

With CO; In chloroform; pressure reactor, p(CO): 50 atm, 12 h; soln. was analysed by gas chromatography and 31P-NMR spectroscopy;

DOI:10.1039/DT9880001617

upstream raw materials:

Pt(CO)(PPh₃)3

trans-{PtH(C₃H₄O₂)(PPh₃)2}BF₄

bis(triphenylphosphine)iminium chloride

{η5-Cp(NO)HRe(μ-PCy2)Pt(PPh3)2}(BPh4)

Downstream raw materials:

(PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp

[Pt2(CO)2(PPh3)2(μ-η1:η1-MeO2CC2CO2Me)]