perfluoro-o-phenylenemercury trimer

Base Information

• Chemical Name: perfluoro-o-phenylenemercury trimer
• CAS No.: 18734-63-9
• Molecular Formula: C₁₈F₁₂Hg₃
• Molecular Weight: 1045.95
• Mol file: 18734-63-9.mol

Synonyms:perfluoro-o-phenylenemercury trimer

Chemical Property of perfluoro-o-phenylenemercury trimer

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of perfluoro-o-phenylenemercury trimer

There total 1 articles about perfluoro-o-phenylenemercury trimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4,5,6-tetrafluorophthalic acid (652-03-9) + mercury(II) diacetate (1600-27-7) → bis(2,3,4,5-tetrafluorophenyl)mercury (22871-68-7) + perfluoro-o-phenylenemercury trimer (18734-63-9)

Guidance literature:

In neat (no solvent); (a) warm aq. soln. of tetrafluorophthallic acid mixed with Hg(CH3CO2)2 soln., ppt. filtered, dried at 110°C, (b) decarboxylated and sublimed at 300°C (vac.); dissolved in DMF, filtered, treated with H2O vapour, dried at 150°C, recrystd. (cyclohexanone), dried;

DOI:10.1016/S0022-328X(00)86660-7

Reference yield: 100.0%

perfluoro-o-phenylenemercury trimer (18734-63-9) + acetophenone (98-86-2) → [(Hg(perfluoro-ortho-phenylene))3(μ-3-acetophenone)]

Guidance literature:

In neat (no solvent); slow concn. of acetophenone-soln. (fume hood);

DOI:10.1021/om020276a

Reference yield: 99.0%

perfluoro-o-phenylenemercury trimer (18734-63-9) + toluene (108-88-3,15644-74-3,16713-13-6) → perfluoro-ortho-phenylene mercury trimer - toluene (1:1) (649559-05-7)

Guidance literature:

In toluene; Hg-compound was dissolved by boiling in toluene, cooled; slow evapd. in a well-aerated fume hood; elem. anal.;

DOI:10.1039/b304023b

upstream raw materials:

3,4,5,6-tetrafluorophthalic acid

mercury(II) diacetate

Downstream raw materials:

[tris(perfluoro-o-phenylene mercury)-(2-(phenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)-tris(perfluoro-o-phenylene mercury)]

octafluorodibenzothiophene

perfluoroselenanthrene

1,2-bis(bromomercurio)tetrafluorobenzene