N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

Base Information

Chemical Name:N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide
CAS No.:1345730-73-5
Molecular Formula:C₁₈H₂₅NO₅
Molecular Weight:335.4
Hs Code.:

Synonyms:N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

Suppliers and Price of N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

There total 1 articles about N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 1345730-73-5
N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate / diethyl ether / 20 °C

2: tert.-butylhydroperoxide; 1,10-Phenanthroline; Copper(I); benzoate; sodium hydrogencarbonate / decane; dimethyl sulfoxide / 0.5 h / 20 °C / Inert atmosphere

With tert.-butylhydroperoxide; 1,10-Phenanthroline; boron trifluoride diethyl etherate; Copper(I); benzoate; sodium hydrogencarbonate; In diethyl ether; decane; dimethyl sulfoxide;
DOI:10.1021/ol201629n

Reference yield: 92.0%

: 1345730-73-5
N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

: 762-42-5
dimethyl acetylenedicarboxylate

: 1316673-74-1
dimethyl 2-(1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-yl)-3-phenyl-2,3-dihydroisoxazole-4,5-dicarboxylate

Guidance literature:: In benzene; at 20 ℃; for 7h; optical yield given as %de; Molecular sieve;
DOI:10.1021/ol201629n

Reference yield: 90.0%

: 1345730-73-5
N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide

: 89343-06-6
tris-iso-propylsilyl acetylene

: 1316673-78-5
methyl 2-(hydroxy(1-phenyl-3-(triisopropylsilyl)prop-2-yn-1-yl)amino)-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propanoate

Guidance literature:: tris-iso-propylsilyl acetylene; With diethylzinc; In hexane; benzene; at 0 ℃; for 0.0833333h; Molecular sieve;

N-benzylidene-1-methoxy-1-oxo-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propan-2-amine N-oxide; In hexane; benzene; at 0 - 20 ℃; optical yield given as %de;
DOI:10.1021/ol201629n