2-(Perfluorododecyl)ethanol

Base Information

• Chemical Name: 2-(Perfluorododecyl)ethanol
• CAS No.: 39239-77-5
• Molecular Formula: C14H5F25O
• Molecular Weight: 664.153
• Hs Code.: 2905599890
• European Community (EC) Number: 254-373-1
• UNII: 47BGO880HN
• DSSTox Substance ID: DTXSID3068170
• Nikkaji Number: J261.347F
• Wikidata: Q27259040
• Mol file: 39239-77-5.mol

Synonyms:2-(Perfluorododecyl)ethanol;39239-77-5;1,1,2,2-Tetrahydroperfluoro-1-tetradecanol;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecan-1-ol;EINECS 254-373-1;UNII-47BGO880HN;47BGO880HN;1-Tetradecanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-;1-Tetradecanol,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-Pentacosafluorotetradecanol;1h,1h,2h,2h-perfluorotetradecan-1-ol;n:2 FTOHs n=6;PFA 12;SCHEMBL3133329;2-Perfluorododecyl ethyl alcohol;DTXSID3068170;12:2 FTOH;C14H5F25O;C14 Gamma-Omega Perfluoro Alcohol;C14-H5-F25-O;2-(PERFLUORODODECYL)ETHYL ALCOHOL;1H,1H,2H,2H-PERFLUOROTETRADECANOL;1,1,2,2-TETRAHYDROPERFLUORO-TETRADECANOL;Q27259040;2-[6-(Tridecafluorohexyl)-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexyl]ethanol;1-Tetradecanol, 3,3,4,4,5,5,6,6,7,7,8,8,9, 9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro -

Chemical Property of 2-(Perfluorododecyl)ethanol

Chemical Property:

• Vapor Pressure: 0.00261mmHg at 25°C
• Refractive Index: 1.293
• Boiling Point: 254.6°Cat760mmHg
• Flash Point: 107.8°C
• PSA: 20.23000
• Density: 1.686g/cm³
• LogP: 7.91940
• XLogP3: 8.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 26
• Rotatable Bond Count: 12
• Exact Mass: 663.9941188
• Heavy Atom Count: 40
• Complexity: 909

Purity/Quality:

99% ^*data from raw suppliers

1,1,2,2-Tetrahydroperfluoro-1-tetradecanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CO)C(C(C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 1,1,2,2-Tetrahydroperfluoro-1-tetradecanol is an important group of organic environmental contaminant.

Technology Process of 2-(Perfluorododecyl)ethanol

There total 7 articles about 2-(Perfluorododecyl)ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

potassium 14,14,14,13,13,12,12,11,11,10,10,9,9,8,8,7,7,6,6,5,5,4,4,3,3-pentacosafluorotetradecyl sulfate (1262446-15-0) → 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5)

Guidance literature:

With hydrogenchloride; water; at 70 ℃; for 25h; pH=0 - 1;

DOI:10.1016/j.jfluchem.2010.09.004

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + 1H,1H,2H,2H-tridecafluoro-n-octanol (647-42-7) + 2-(perfluorodecyl)ethanol (865-86-1) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene (25291-17-2) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + C14F29CH=CH2 (104564-28-5) + C16F33CH=CH2 + 1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + C18F37CH2CH2OCOCH=CH2 (65104-64-5) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

upstream raw materials:

1-iodo-1H,1H,2H,2H-perfluorohexadecane

3,3,4,4,5,5,6,6,6-nonafluorohexyliodide

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

2-(n-perfluorooctyl)ethyl iodide

Downstream raw materials:

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate

C₁₄F₂₉CH₂CH₂OCOCH=CH₂

1H,1H,2H,2H-heptadecafluorodecyl acrylate

1,1,2,2-Tetrahydroperfluorododecyl acrylate