Ru(C≡CC≡CSiMe₃)(dppe)Cp*

Base Information

Chemical Name:Ru(C≡CC≡CSiMe₃)(dppe)Cp*
CAS No.:717110-27-5
Molecular Formula:C₄₃H₄₈P₂RuSi
Molecular Weight:755.957
Hs Code.:

Synonyms:Ru(C≡CC≡CSiMe₃)(dppe)Cp*

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Chemical Property of Ru(C≡CC≡CSiMe₃)(dppe)Cp*

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Technology Process of Ru(C≡CC≡CSiMe₃)(dppe)Cp*

There total 4 articles about Ru(C≡CC≡CSiMe₃)(dppe)Cp* which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 109-72-8,29786-93-4
n-butyllithium

: 75-77-4
chloro-trimethyl-silane

: 649720-49-0
Ru(C≡CC≡CH)(dppe)Cp*

: 717110-27-5
Ru(C≡CC≡CSiMe₃)(dppe)Cp*

Guidance literature:: In tetrahydrofuran; (N2); treatment of soln. of Ru(CCCCH)(dppe)(C5Me5) in THF with soln. of LiBu (2 equiv.) in THF at -78°C and stirring for 30 min, addn. ofSiClMe3, warming to room temp. over 2 h; removal of solvent, dissolving in hexane, filtration via cannula, evapn.to dryness; elem. anal.;
DOI:10.1016/j.jorganchem.2011.07.021

Reference yield: 79.0%

: pentamethylcyclopentadienyl(1,2-bis(diphenylphosphino)ethane)chlororuthenium(II)

: 4526-06-1
trimethylsilyl-1,3-butadiyne

: 717110-27-5
Ru(C≡CC≡CSiMe₃)(dppe)Cp*

Guidance literature:: With NaBPh₄; In tetrahydrofuran; triethylamine; under Ar atm to suspn. RuCl(dppe)Cp* and NaBPh4 in THF-NEt3 HCCCCSiMe3 was added andwarmed at 50°C for 48 h; solvent was removed, residue was extd. with hexane and concd., ppt. was dried; elem. anal.;
DOI:10.1039/b316297b

Reference yield: 75.0%

: 75-77-4
chloro-trimethyl-silane

: 649720-49-0
Ru(C≡CC≡CH)(dppe)Cp*

: 594-19-4
tert.-butyl lithium

: 717110-27-5
Ru(C≡CC≡CSiMe₃)(dppe)Cp*

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2); treatment of soln. of Ru(CCCCH)(dppe)(C5Me5) in THF with soln. of Li(t-Bu) (1 equiv.) in Et2O at -80°C and stirring for 1 h, addn. of SiClMe3, warming to room temp. over 2 h; removal of solvent, dissolving in hexane, filtration via cannula, evapn.to dryness;
DOI:10.1016/j.jorganchem.2011.07.021