phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Base Information

Chemical Name:phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside
CAS No.:188583-26-8
Molecular Formula:C₂₆H₂₅Cl₆NO₉S
Molecular Weight:740.27
Hs Code.:

phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Synonyms:phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Suppliers and Price of phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

There total 6 articles about phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 188583-25-7
phenyl 2-[(2,2,2-trichloroethoxy)carbonyl]amino-4,6-O-p-methoxybenzylidene-2-deoxy-1-thio-β-D-glucopyranoside

: 17341-93-4
2,2,2-Trichloroethyl chloroformate

: 188583-26-8
phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: With pyridine; dmap; In dichloromethane; for 10h; Ambient temperature;
DOI:10.1248/cpb.45.312

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 188583-26-8
phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / p-TsOH / dimethylformamide / 2 h / Ambient temperature

2: 93 percent / 4-dimethylaminopyridine, pyridine / CH₂Cl₂ / 10 h / Ambient temperature

With pyridine; dmap; toluene-4-sulfonic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1248/cpb.45.312

Reference yield:

: 108-98-5
thiophenol

: 188583-26-8
phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / BF₃*Et₂O / CH₂Cl₂ / 24 h / Ambient temperature

2: 88 percent / NaOMe / methanol / 0.33 h / 0 °C

3: 87 percent / p-TsOH / dimethylformamide / 2 h / Ambient temperature

4: 93 percent / 4-dimethylaminopyridine, pyridine / CH₂Cl₂ / 10 h / Ambient temperature

With pyridine; dmap; boron trifluoride diethyl etherate; sodium methylate; toluene-4-sulfonic acid; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1248/cpb.45.312