1-(3-Chlorophenyl)-1,2-ethane dithiocyanate

Base Information

• Chemical Name: 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate
• CAS No.: 115584-30-0
• Molecular Formula: C₁₀H₇ClN₂S₂
• Molecular Weight: 254.764
• Mol file: 115584-30-0.mol

Synonyms:1-(3-Chlorophenyl)-1,2-ethane dithiocyanate

Chemical Property of 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate

There total 3 articles about 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

3-Chlorostyrene (2039-85-2,26100-04-9) + potassium thioacyanate (333-20-0) → 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate (115584-30-0)

Guidance literature:

With iron(III) chloride; In acetonitrile; at 20 ℃; for 3h;

DOI:10.1055/s-2004-829150

Reference yield: 78.0%

3-Chlorostyrene (2039-85-2,26100-04-9) + ammonium thiocyanate (1147550-11-5) → 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate (115584-30-0)

Guidance literature:

With Selectfluor; copper(I) bromide; In dichloromethane; at 90 ℃; for 3h; chemoselective reaction; Sealed tube;

DOI:10.1080/00397911.2016.1194997

Reference yield:

thiocyanogen (505-14-6) + 3-Chlorostyrene (2039-85-2,26100-04-9) + acetic acid (64-19-7,77671-22-8) → 1-(3-Chlorophenyl)-1,2-ethane dithiocyanate (115584-30-0) + 1-(3-Chlorophenyl)-1-isothiocyanato-2-thiocyanatoethane (115584-31-1) + 2-(3-Chlorophenyl)-2-acetoxyethane thiocyanate (115584-32-2)

Guidance literature:

lithium perchlorate; at 40 ℃; Product distribution; Rate constant; Mechanism; without LiClO₄;

upstream raw materials:

thiocyanogen

3-Chlorostyrene

acetic acid

potassium thioacyanate