[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Base Information

Chemical Name:[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]
CAS No.:431882-00-7
Molecular Formula:C₁₅H₂₉Cl₂PRh*C₃₂H₁₂BF₂₄
Molecular Weight:1277.4
Hs Code.:

[(C<sub>5</sub>(CH<sub>3</sub>)5)(P(CH<sub>3</sub>)3)Rh(CH<sub>3</sub>)(dichloromethane)][B(3,5-C<sub>6</sub>H<sub>3</sub>(CF<sub>3</sub>)2)4]

Synonyms:[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Suppliers and Price of [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

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Technology Process of [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

There total 1 articles about [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: Rh(C₅(CH₃)5)P(CH₃)3(CH₃)CF₃SO₃

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 431882-00-7
[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Guidance literature:: In dichloromethane; byproducts: NaCl; Rh-complex and Na-salt were sealed, placed in ice bath, CH2Cl2 was introduced, stirred for 10-15 min; filtered, concd. in vacuo, placed in freezer at 243 K for 2 d;
DOI:10.1021/ja0165990

Reference yield: 99.0%

: 431882-00-7
[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

: 789-25-3
HSiPh₃

: 431882-02-9
[(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Guidance literature:: In dichloromethane; byproducts: CH4; the react. was complete within a few s at 25°C;
DOI:10.1021/ja0255094

Reference yield: 99.0%

: 431882-00-7
[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

: 100-47-0
benzonitrile

: 789-25-3
HSiPh₃

: 431882-14-3
[(C₅(CH₃)5)(P(CH₃)3)Rh(C₆H₅)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Guidance literature:: In dichloromethane; byproducts: CH4; Rh complex was treated with (C6H5)3SiH at 25°C for a few s and then reacted with the nitrile at 25°C for 1 h;
DOI:10.1021/ja0255094