Titanium tetraisopropanolate

Base Information Edit

Chemical Name:Titanium tetraisopropanolate
CAS No.:546-68-9
Deprecated CAS:112797-74-7,118815-04-6,119651-13-7,128796-34-9,131530-94-4,147809-57-2,167709-32-2,176680-01-6,186518-71-8,187601-75-8,195382-13-9,198699-88-6,210407-18-4,216859-04-0,3651-85-2,50336-56-6,71515-81-6,73264-97-8,94340-28-0,366477-01-2,347859-73-8,310882-94-1,259264-35-2,244173-55-5,245654-31-3,255839-65-7,408306-55-8,505093-57-2,518050-49-2,300564-30-1,917485-01-9,918419-31-5,1004522-95-5,1016644-08-8,1149373-13-6,1245903-59-6,1352612-45-3,2120427-28-1,2408830-00-0,2448474-28-8
Molecular Formula:C12H28O4Ti
Molecular Weight:284.232
Hs Code.:29051900
European Community (EC) Number:208-909-6
UN Number:1993
UNII:76NX7K235Y
Nikkaji Number:J6.429G
Wikipedia:Titanium_isopropoxide
Wikidata:Q2031021
Mol file:546-68-9.mol

Synonyms:tetraisopropyl titanate;Ti(IV) isopropoxide;Ti(OiPr)4;titanium isopropoxide;titanium tetraisopropoxide;titanium(IV) isopropoxide

Suppliers and Price of Titanium tetraisopropanolate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Tetraisopropyl Orthotitanate
25g
$ 425.00

TRC
Titanium(IV) isopropoxide
1g
$ 115.00

TCI Chemical
Tetraisopropyl Orthotitanate
25g
$ 16.00

TCI Chemical
Tetraisopropyl Orthotitanate
500g
$ 50.00

Strem Chemicals
Titanium(IV) i-propoxide, min. 98%
250g
$ 43.00

Strem Chemicals
Titanium(IV) i-propoxide, min. 98%
1kg
$ 130.00

Strem Chemicals
Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok(R) cylinder (96-1070) for CVD/ALD
25g
$ 657.00

Sigma-Aldrich
Titanium(IV) isopropoxide packaged for use in deposition systems
25g
$ 818.00

Sigma-Aldrich
Titanium(IV) isopropoxide 99.999% trace metals basis
100ml
$ 401.00

Sigma-Aldrich
Titanium(IV) isopropoxide ≥97.0%
500ml
$ 107.00

Total 89 raw suppliers

Chemical Property of Titanium tetraisopropanolate Edit

Chemical Property:

Appearance/Colour:colourless to light yellow liquid
Vapor Pressure:81.3mmHg at 25°C
Melting Point:14-17 °C(lit.)
Refractive Index:n20/D 1.464(lit.)
Boiling Point:232 °C(lit.)
Flash Point:72 °F
PSA：36.92000
Density:0.96 g/mL at 20 °C
LogP:3.50280
Storage Temp.:Flammables area
Sensitive.:Moisture Sensitive
Solubility.:Soluble in anhydrous ethanol, ether, benzene and chloroform.
Water Solubility.:HYDROLYSIS
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:284.1467000
Heavy Atom Count:17
Complexity:10.8
Transport DOT Label:Flammable Liquid

Purity/Quality:

98% ^*data from raw suppliers

Tetraisopropyl Orthotitanate ^*data from reagent suppliers

Safty Information:

Pictogram(s): F, Xi
Hazard Codes:Xi,F
Statements: 10-36-36/37/38-11-67
Safety Statements: 16-26-36/37/39-7/9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Metals -> Metal Alkoxides
Canonical SMILES:CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-].[Ti+4]
Uses Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process. Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.

Technology Process of Titanium tetraisopropanolate

There total 27 articles about Titanium tetraisopropanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%